EM SCIENCE -- METHANOL, 0427339 -- 6810-00N071606
===================== Product Identification ===================== Product ID:METHANOL, 0427339 MSDS Date:08/31/1995 FSC:6810 NIIN:00N071606 === Responsible Party === Company Name:EM SCIENCE Address:480 DEMOCRAT RD Box:70 City:GIBBSTOWN State:NJ ZIP:08027 Country:US Info Phone Num:609-354-9200 Emergency Phone Num:800-424-9300 (CHEMTREC) CAGE:DO242 === Contractor Identification === Company Name:E M SCIENCE DIV OF E M INDUSTRIES INC Address:480 DEMOCRAT ROAD Box:70 City:GIBBSTOWN State:NJ ZIP:08027 Country:US Phone:800-222-0342/609-423-6300 CAGE:63612 Company Name:EM SCIENCE Address:480 DEMOCRAT RD City:GIBBSTOWN State:NJ ZIP:08927 Phone:800-424-9300 (CHEMTREC) CAGE:DO242 ============= Composition/Information on Ingredients ============= Ingred Name:METHANOL (SARA 313) (CERCLA) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 100% OSHA PEL:200 PPM, S ACGIH TLV:200PPM/250STEL, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SUP DAT: VACUUM IF SUBJECTED TO SUDDEN INGRESS OF AIR/OUTSIDE PROCESS EQUIP OPERATING UNDER ELEVATED PRESS IF (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: SUDDEN ESCAPE OF VAPS/MISTS TO THE ATMOSPHERE OCCURS. RTECS #:9999999ZZ Ingred Name:SPILL PROC: CONTAINERIZE FOR PROPER DISP AS DESCRIBED UNDER DISP. COMPLY W/FED, STATE & LOC REGS ON REPORTING (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: RELEASES. REFER TO REGULATORY INFO FOR REPORTABLE QTY & OTHER REGULATORY DATA. THE FOLLOWING EM SCIENCE (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: SPILL-X ABSORBENT IS RECOMMENDED FOR THIS PRODUCT: SX0863 SOLVENT SPILL TREATMENT KIT. RTECS #:9999999ZZ Ingred Name:RESP PROT: SPECIFIED CNDTNS (SEE YOUR SFTY EQUIP SUPP). ENGINEERING &/ADMIN CTLS SHOULD BE IMPLEMENTED TO REDUCE EXPOS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): 5628 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: TOX BY INGEST & INHAL. CAN BE TOX BY SKIN ABSORPTION. AFTER INGEST/INHAL, INITIAL SYMPS MAY BE ONLY THAT OF MILD INTOXICATION, BUT MAY BECOME SEV AFTER 12 TO 18 HRS. AFFECTS CNS, ESP OPTIC NERV E. CHRONIC: MARKED IMPAIRMENT OF VISION& ENLARGEMENT OF LIVER HAS BEEN REPORTED W/CHRONIC EXPOS. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: CHRONIC EXPOS MAY ALSO CAUSE DMG TO KIDNEYS & CNS. CAUSES DIZZ, NAUS, MUSCLE WEAK, NARCOSIS, RESP FAILURE. INGEST CAN PRDCE BLINDNESS (100 ML CAN BE FATAL). Medical Cond Aggravated by Exposure:SKIN CONDITIONS, EYE PROBLEMS, OR IMPAIRED LIVER OR KIDNEY FUNCTION. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXP. SKIN: WASH THORO W/SOAP & WATER. EYES: IMMED FLUSH THORO W/WATER FOR AT LEAST 15 MINUTES. INHAL: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF BR EATHING HAS STOPPED. INGESTION: GET IMMED MED ATTENTION. IF MED ATTN IS NOT IMMED AVAILABLE, INDUCE VOMIT. DO NOT INDUCE VOMIT IF PATIENT IS UNCON. REMOVE CONTAM CLTHG & WASH BEFORE REUSE. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:52.0F,11.1C Lower Limits:6.7% Upper Limits:36.5% Extinguishing Media:USE DRY CHEMICAL, "ALCOHOL" FOAM, CARBON DIOXIDE, WATER MIST. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:DANGEROUS FIRE & EXPLO HAZ. CLSD CONTRS MAY EXPLODE UPON HEATING. VAP CAN TRAVEL DISTANCES TO IGNIT SOURCE & FLASH BACK. HOT ORG CHEM VAPS/MISTS ARE (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA OF ALL UNNEC PERS. WEAR SUITABLE PROT EQUIP LISTED UNDER "CTL MEASURES". ELIM ANY IGNIT SOURCES UNTIL AREA IS DETERM TO BE FREE FROM EXPLO/FIRE HAZ. CONTAIN RELEASE & ELIM ITS SOURCE, IF THIS CAN BE DONE W/OUT RISK. TAKE UP &(ING 4) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN A COOL AREA AWAY FROM IGNITION SOURCES AND OXIDIZERS. DO NOT BREATHE VAPOR OR SOLUTION MIST. Other Precautions:DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. ELECTRICALLY GROUND ALL EQUIPMENT WHEN HANDLING THIS PRODUCT. DO NOT TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKPLACE EXPOS LIM OF PROD/ANY COMPONENT IS EXCEEDED (SEE TLV/PEL), A NIOSH/MSHA APPRVD AIR SUPP RESP IS ADVISED IN ABSENCE OF PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT OTHER NIOSH/MSHA APPRVD RES PS (NEG PRESS TYPE) UNDER (ING 7) Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION. Protective Gloves:BUTYL RUBBER GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS . Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health EXPLO HAZ: SUSCEPTIBLE TO SUDDEN SPONT COMBUST WHEN MIXED W/AIR. IGNIT MAY OCCUR AT TEMPS < PUBLISHED AUTOIGNIT/IGNIT TEMPS. IGNIT TEMPS DECR W/INCRG VAP VOL & VAP/AIR CONT TIME & ARE INFLUENCED BY PR ESS CHANGES. IGNIT MAY OCCUR AT TYPICALELEVATED TEMP PROCESS CNDTNS, ESPECIALLY IN PROCESS OPERATING UNDER (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:148F,65C Melt/Freeze Pt:M.P/F.P Text:-144F,-98C Vapor Pres:9.7 @ 20C Vapor Density:1.1 Spec Gravity:0.791 Evaporation Rate & Reference:5.91 Solubility in Water:MISCIBLE Appearance and Odor:COLORLESS LIQUID, WITH CHARACTERISTIC ALCOHOLIC ODOR Percent Volatiles by Volume:>99.9 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, OXIDIZERS, REACTIVE METALS. Stability Condition to Avoid:HEAT; CONTACT WITH IGNITION SOURCE. Hazardous Decomposition Products:CO*X, FORMALDEHYDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:EPA WASTE NUMBERS: U154 D001. TREATMENT: INCIN, FUELS BLENDING/RECYCLE. CONT YOUR LOC PERMITTED WASTE DISP SITE (TSD) FOR PERMISSIBLE TREATMENT SITES. ALWAYS CONT PERMITTED WASTE DISP (TSD) TO ASSURE COMPLIANCE W/ALL CURRENT LOC, STATE & FED REGS. 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