NOVARTIS CROP PROTECTION, INC (CIBA-GEIGY CORP) -- PRAMITOL 5PS -- 6840-00-180-6386
===================== Product Identification ===================== Product ID:PRAMITOL 5PS MSDS Date:10/12/1993 FSC:6840 NIIN:00-180-6386 === Responsible Party === Company Name:NOVARTIS CROP PROTECTION, INC (CIBA-GEIGY CORP) Address:410 SWING ROAD Box:18300 City:GREENSBORO State:NC ZIP:27419 Country:US Info Phone Num:919-292-7100 Emergency Phone Num:800-888-8372 OR 800-334-9481 CAGE:KO472 === Contractor Identification === Company Name:ABC SUPPLY CO Address:654 S WHEELING Box:334 City:WHEELING State:IL ZIP:60090 Country:US Phone:708-459-7788 CAGE:1EV32 Company Name:CIBA-GEIGY CORP, AGRICULTURAL DIV. Address:410 SWING ROAD Box:18300 City:GREENSBORO State:NC ZIP:27419 Phone:800-888-8372 OR 800-334-9481 CAGE:8K340 Company Name:EHRLICH J C CHEMICAL CO INC Address:500 SPRING RIDGE DR Box:City:READING State:PA ZIP:19612-3848 Country:US Phone:610-372-9700/FAX: 610-378-9744 CAGE:8C885 Company Name:GOURMET INQUE LTD Address:191 STANLEY ST Box:City:ELK GROVE VILLAGE State:IL ZIP:60007-1555 Country:US Phone:847-296-6192/FAX: 800-542-1042 CAGE:0TNN7 Company Name:NOVARTIS CROP PROTECTION, INC (CIBA-GEIGY CORP) Address:410 SWING ROAD Box:18300 City:GREENSBORO State:NC ZIP:27419 Country:US Phone:919-292-7100/800-888-8372 CAGE:KO472 ============= Composition/Information on Ingredients ============= Ingred Name:PRIMATOL (PROMETONE) CAS:1610-18-0 RTECS #:XY4200000 Fraction by Wt: 5% Other REC Limits:NONE SPECIFIED Ingred Name:2-CHLORO-4.6-BIS(ETHYLAMINO)-S-TR1AZINE CAS:122-34-9 RTECS #:XY5250000 Fraction by Wt: 0.8% Other REC Limits:NONE SPECIFIED Ingred Name:SODIUM CHLORATE CAS:7775-09-9 RTECS #:FO0525000 Fraction by Wt: 40% Other REC Limits:NONE SPECIFIED Ingred Name:SODIUM TETRABORATE, DECAHYDRATE CAS:1303-96-4 RTECS #:VZ2275000 Fraction by Wt: 50% Other REC Limits:NONE SPECIFIED OSHA PEL:10 MG/M3 ACGIH TLV:5 MG/M3; 9495 Ingred Name:INERT INGREDIENTS Fraction by Wt: 4.25% Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) = 2745 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYE:CORROSIVE ON CONTACT. SKIN:EXTREMELY IRRITATING. SLIGHTLY TOXIC BY ABSORPTION. INHALATION:SLIGHTLY TOXIC. INGESTION:SLIGHTLY TOXIC. Explanation of Carcinogenicity:MANUFACTURER GAVE NO INFORMATION ABOUT CARCINOGENICITY. HMIS FOUND NO LISTING & DOES NOT EXPECT IT TO BE CARCINOGENIC. Effects of Overexposure:EXPOSURE TO PRAMITOL 5PS CAN CAUSE IRREVERSIBLE EYE DAMAGE & CHEMICAL BURNS TO THE SKIN. IF SWALLOWED IT MAY DAMAGE MUCOUS MEMBRANES RESULTING IN BREATHING DUFFICULTY, ABDOMINAL PAIN, NAUSEA, VOMITING , GASTRITIS, WEAKNESS, DIARRHEA. INGESTION OF A LARGE AMOUNT CAN LEAD TO CYANOSIS & HEMATURIA. Medical Cond Aggravated by Exposure:PERSONS W/PREEXISTING RESPIRATORY DISORDERS, ALLERGY HISTOTY OR DERMATITIS SHOULD USE EXTRA CARE IN HANDLING THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:IN CASE OF CONTACT, DO NOT APPLY ANY MEDICATION, GET MEDICAL ATTENTION. EYE:FLUSH W/WATER FOR 15 MIN. SKIN:WASH W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. INHALED:REMOVE FROM EXPOSURE. AID OR RESTORE BREATHING AS NEEDED. INGESTED:IF FULLY CONSCIOUS, GIVE 1-2 GLASSES OF WATER TO DRINK & INDUCE VOMITING. NOTHING BY MOUTH IF UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point:N/A. Autoignition Temp:Autoignition Temp Text:N/A. Lower Limits:N/A. Upper Limits:N/A. Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. EVACUATE NON-ESSENTIAL PERSONNEL. DO NOT USE CONTAMINATED BUILDINGS UNTIL AFTER CLEANING. Unusual Fire/Explosion Hazard:SODIUM CHLORATE CAN REACT W/OTHER MATERIALS TO CAUSE FIRE OR EXPLOSIVE MIXTURES. IN THIS FORMULATION SODIUM CHLORATE COMBINED W/SODIUM METABORATE IS NEUTRALIZED ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT INCLUDING APPROVED DUST RESPIRATOR. SMALL SPILLS:SWEEP UP & PLACE IN A DISPOSAL CONTAINER. WASH THE SPILL AREA WITH A STRONG DETERGENT SOLUTION & ABSORB WITH INERT MATERIAL. KEEP CLEAN-UP WATER FROM WATER SUPPLIES. Neutralizing Agent:MFR GAVE NO INFORMATION OF MSDS. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A WELL VENTILATED SECURE AREA AWAY FROM CHILDERN & DOMESTIC ANIMALS. DO NOT STORE FOOD, BEVERAGES OR TOBACCO PRODUCTS IN STORAGE AREA. Other Precautions:PREVENT EATING, DRINKING, TOBACCO USE & COSMETIC APPLICATION WHERE THERE IS POTENTIAL FOR EXPOSURE TO THE MATERIAL. ALWAYS WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A NIOSH APPROVED DUST OR PESTICIDE RESPIRATOR Ventilation:MFR GAVE NO INFORMATION OF MSDS. Protective Gloves:RUBBER GLOVES Eye Protection:CHEMICAL GOGGLES OR A FACE SHIELD Other Protective Equipment:RUBBER BOOTS, LONG-SLEEVED SHIRT, LONG PANTS & HAT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT STORE OR USE FOOD, BEVERAGES OR TOBACCO PRODUCTS IN AREA. Supplemental Safety and Health NOTE TO PHYSICIAN: THERE IS NO SPECIFIC ANTIDOTE FOR INGESTION. CHECK FOR COMPROMISED AIRWAY BEFORE INDUCING EMESIS OR PERFORMING LAVAGE. 5 MG/KG OF ACTIVATED CHARCOAL SUSPENSION (50G/400 ML WATER) CA N BE GIVEN TO ABSORB TOXICANT. SALINE LAXATIVE MAY BE GIVEN. MONITOR METHEMOGLOBIN. CONTROL CONVULSIONS. ================== Physical/Chemical Properties ================== HCC:N1 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:N/A. Melt/Freeze Pt:M.P/F.P Text:194F,90C Vapor Pres:N/A. Spec Gravity:58.9 LB/FT3 Evaporation Rate & Reference:N/A. Solubility in Water:750 MG/L Appearance and Odor:ODORLESS, WHITE PELLETS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, ORGANIC COMPOUNDS, PHOSPHORUS, SULFUR, SULFIDES, AMMONIUM COMPOUNDS, & POWDERED METALS. Stability Condition to Avoid:COMBUSTIBLES, HEAT Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE. NITROGEN AND SULFUR COMPOUNDS. CHLORINE AND CHLORINE DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT REUSE CONTAINERS. DISPOSE OF CONTAINERS, WASTES, RESIDUES I/A/W FEDERAL, STATE & LOCAL REGULATIONS. QUESTIONS CONCERNING SAFE HANDLING, CALL CIBA-GEIGY, 800-334-9481. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.