Material Safety Data
Sheet
Sodium Tetraborate Decahydrate
ACC# 21010
Section 1 - Chemical Product and Company
Identification |
MSDS Name: Sodium Tetraborate
Decahydrate
Catalog Numbers: S80172, B80, BP175 500,
BP175-500, BP175500, S246-12, S246-212, S246-250LB, S246-500, S248-10, S248-3,
S248-500, S249-500
Synonyms: Buffer Salt pH 9.18; Borax, Sodium
Borate Decahydrate
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance,
call: 800-424-9300
For International CHEMTREC assistance, call:
703-527-3887
Section 2 -
Composition, Information on Ingredients |
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
1303-96-4 |
Sodium Tetraborate Decahydrate |
100 |
unlisted
|
Hazard Symbols: None listed.
Risk Phrases: None listed.
Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white. May cause irritation. May cause eye and skin irritation.
May cause respiratory and digestive tract irritation. May cause adverse
reproductive effects based upon animal studies. Caution!
Target Organs: None.
Potential Health
Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation.
Ingestion: May cause irritation of the digestive tract.
Human fatalities have been reported from acute poisoning.
Inhalation: May cause respiratory tract irritation.
Chronic: No information found.
Section 4 - First Aid
Measures |
Eyes: Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get
medical aid.
Skin: Flush skin with plenty of soap and water
for at least 15 minutes while removing contaminated clothing and shoes. Get
medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Get medical aid. Do NOT induce vomiting. If
conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash
mouth out with water.
Inhalation: Remove from exposure to
fresh air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical aid if cough or other symptoms
appear.
Notes to Physician: Treat symptomatically and
supportively.
Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Runoff from fire control or dilution water
may cause pollution.
Extinguishing Media: Use agent most
appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide,
or appropriate foam.
Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Vacuum or sweep up material and
place into a suitable disposal container. Clean up spills immediately, observing
precautions in the Protective Equipment section. Avoid generating dusty
conditions. Provide ventilation.
Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Use with
adequate ventilation. Minimize dust generation and accumulation. Avoid contact
with eyes, skin, and clothing. Do not breathe dust, vapor, mist, or gas. Keep
container tightly closed. Avoid ingestion and inhalation.
Storage: Store in a tightly closed container. Store in a
cool, dry, well-ventilated area away from incompatible substances.
Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Facilities storing or utilizing this material should be
equipped with an eyewash facility and a safety shower. Use adequate ventilation
to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
Sodium Tetraborate Decahydrate |
1 mg/m3 TWA (anhydrous); 5 mg/m3 TWA (decahydrate); 1
mg/m3 TWA (pentahydrate) |
5 mg/m3 TWA |
none
listed |
OSHA Vacated PELs: Sodium
Tetraborate Decahydrate: 10 mg/m3 TWA
Personal Protective
Equipment
Eyes: Wear appropriate protective
eyeglasses or chemical safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin
exposure.
Clothing: Wear appropriate protective clothing to
prevent skin exposure.
Respirators: A respiratory protection program
that meets OSHA's 29 CFR �1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace conditions warrant a
respirator's use.
Section 9 - Physical
and Chemical Properties |
Physical State:
Solid
Appearance: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not
available.
Viscosity: Not available.
Boiling Point: 1575
deg C @ 760.00mm Hg
Freezing/Melting Point:320 deg C
Autoignition Temperature: Not available.
Flash Point: Not
available.
Decomposition Temperature:Not available.
NFPA
Rating: (estimated) Health: 2; Flammability: 0; Reactivity: 0
Explosion Limits, Lower:Not available.
Upper: Not
available.
Solubility: soluble
Specific
Gravity/Density:1.7300g/cm3
Molecular Formula:B4Na2O7.10H2O
Molecular Weight:381.36
Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable at room temperature in closed containers under normal
storage and handling conditions.
Conditions to Avoid: Incompatible
materials, dust generation, excess heat.
Incompatibilities with Other
Materials: Strong oxidizing agents, strong acids.
Hazardous
Decomposition Products: Irritating and toxic fumes and gases, oxides of
boron.
Hazardous Polymerization: Will not occur.
Section 11 -
Toxicological Information |
RTECS#:
CAS# 1303-96-4: VZ2275000
LD50/LC50:
CAS#
1303-96-4:
Oral, mouse: LD50 = 2 gm/kg;
Oral, rat: LD50 = 2660
mg/kg;
Carcinogenicity:
CAS# 1303-96-4: Not listed by
ACGIH, IARC, NIOSH, NTP, or OSHA.
Epidemiology: No information
available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Neurotoxicity: No information available.
Mutagenicity: No
information available.
Other Studies: See actual entry in RTECS for
complete information.
Section 12 -
Ecological Information |
No information available.
Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 -
Transport Information |
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US
DOT |
IATA |
RID/ADR |
IMO |
Canada
TDG |
Shipping Name: |
No information available. |
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No information available. |
Hazard Class: |
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UN Number: |
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Packing Group: |
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS# 1303-96-4 is listed on the TSCA
inventory.
Health & Safety Reporting List
None of the
chemicals are on the Health & Safety Reporting List.
Chemical Test
Rules
None of the chemicals in this product are under a Chemical Test
Rule.
Section 12b
None of the chemicals are listed under TSCA
Section 12b.
TSCA Significant New Use Rule
None of the chemicals
in this material have a SNUR under TSCA.
SARA
Section 302
(RQ)
None of the chemicals in this material have an RQ.
Section
302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA
Codes
CAS # 1303-96-4: chronic.
Section 313
No chemicals
are reportable under Section 313.
Clean Air Act:
This material
does not contain any hazardous air pollutants. This material does not contain
any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone
depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA. None of the chemicals in this
product are listed as Priority Pollutants under the CWA. None of the chemicals
in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly
hazardous by OSHA.
STATE
CAS# 1303-96-4 can be found on the
following state right to know lists: California, New Jersey, Florida,
Pennsylvania, Minnesota, Massachusetts.
California No Significant Risk
Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in
Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
Safety Phrases:
WGK (Water
Danger/Protection)
CAS# 1303-96-4: 1
Canada
CAS# 1303-96-4
is listed on Canada's DSL List. CAS# 1303-96-4 is listed on Canada's DSL List.
This product has a WHMIS classification of D2A, D2B.
CAS# 1303-96-4 is
listed on Canada's Ingredient Disclosure List.
Exposure
Limits
CAS# 1303-96-4: OEL-AUSTRALIA:TWA 5 mg/m3 OEL-BELGIUM:TWA 5 mg/m3
OEL-DENMARK:TWA 5 mg/m3 OEL-FRANCE:TWA 5 mg/m3 OEL-THE NETHERLANDS:T
WA 5
mg/m3 OEL-SWEDEN:TWA 2 mg/m3;STEL 5 mg/m3;Skin OEL-SWITZERLAND:
TWA 5 mg/m3
OEL-UNITED KINGDOM:TWA 5 mg/m3 OEL IN BULGARIA, COLOMBIA
, JORDAN, KOREA
check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNA
M check ACGI TLV
Section 16 -
Additional Information |
MSDS Creation Date:
7/06/1999
Revision #4 Date: 7/20/2001
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.