FISHER SCIENTIFIC CHEMICAL DIV -- A669S 500 AMMONIUM HYDROXIDE 01260 -- 6810-00F037967
===================== Product Identification ===================== Product ID:A669S 500 AMMONIUM HYDROXIDE 01260 MSDS Date:12/13/1994 FSC:6810 NIIN:00F037967 === Responsible Party === Company Name:FISHER SCIENTIFIC CHEMICAL DIV Address:1 REAGENT LN City:FAIR LAWN State:NJ ZIP:07410-2802 Country:US Info Phone Num:201-796-7100/201-796-7523 Emergency Phone Num:201-796-7100/201-796-7523 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:AMMONIUM HYDROXIDE, AQUA AMMONIA *98-1* CAS:1336-21-6 RTECS #:BQ9625000 Fraction by Wt: 28-30% Other REC Limits:25 PPM ACGIH TLV:25 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT): 350 MG/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES: SEVERE BURNS & POSSIBLE IRREVERSIBLE DAMAGE. SKIN: SEVERE IRRITATION, BURNS. INGESTION: HARMFUL, MAY CAUSE SEVERE & PERMANENT DAMAGE TO THE DIGESTIVE TRACT, CORROSION & BURNS TO THE GI TRACT. IN HALATION: EFFECTS MAY BE DELAYED, SEVERE IRRITATION OF THE UPPER RESPIRATORY TRACT, BURNS & LUNG DAMAGE. Explanation of Carcinogenicity:NONE Effects of Overexposure:BURNS, IRRITATION, PENETRATING ULCERS, BROWN STAINS, THROAT CONSTRICTION, VOMITING, CONVULSIONS, SHOCK, COUGHING, BREATHING DIFFICULTY, COMA. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: RINSE W/LARGE AMOUNTS OF WATER FOR 15 MINS. INGESTION: DON'T INDUCE VOMITING. IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. NOTES TO PHYSICIAN: AFTER INHALATION, OBSERVE FOR 24-48 HOURS AS PULMONARY EDEMA MAY BE DELAYED. NO SPECIFIC ANTIDOTE. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Lower Limits:16 Upper Limits:25 Extinguishing Media:SMALL: WATER SPRAY, DRY CHEMICAL, CO2/CHEMICAL FOAM. Fire Fighting Procedures:WEAR SCBA IN PRESSURE DEMAND MSHA/NIOSH (APPROVED/EQUIVALENT) & FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:AUTOIGNITION TEMP: 1202F. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB W/INERT MATERIAL, THEN PLACE INTO A CHEMICAL WASTE CONTAINER. NEUTRALIZE W/SODIUM BICARBONATE. ====================== Handling and Storage ====================== Handling and Storage Precautions:USE ONLY IN A WELL VENTILATED AREA. DON'T STORE IN DIRECT SUNLIGHT. STORE IN A COOL, DRY WELL VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:DON'T GET ON SKIN/EYES. DON'T INGEST/INHALE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:GENERAL/LOCAL EXHAUST TO KEEP AIRBORNE CONCENTRATIONS BELOW EXPOSURE LIMITS. Protective Gloves:PROTECTIVE Eye Protection:SAFETY GLASSES W/SIDE SHIELDS Other Protective Equipment:PROTECTIVE CLOTHING. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health MAT TO AVOID: HYDROFLUORIC ACID/IODINE/NITRIC ACID/OLEUM/PROPIOLACTONE/PROPYLENE OXIDE/SILVER NITRATE/SILVER OXIDE/SILVER OXIDE & ETHYL ALCOHOL/NITROMETHANE/SILVER PERMANGANATE/SULFURIC ACID/HALOGENS. FORMS EXPLOSIVE COMPOUNDS W/MANY HEAVYMETALS & HALIDE SALTS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:82.4F Melt/Freeze Pt:M.P/F.P Text:-106.6F Vapor Pres:237.8 Vapor Density:1.2 Spec Gravity:0.9 pH:13.6 Evaporation Rate & Reference:(WATER = 1): 1 Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID W/STRONG AMMONIA ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACROLEIN/ACRYLIC ACID/CHLOROSULFONIC ACID/DIMETHYL SULFATE/FLUORINE/GOLD & AQUA REGIA/HYDORCHLORIC ACID. (SEE SUPP) Stability Condition to Avoid:HIGH TEMPS, INCOMPATIBLE MATERIALS, DIRECT SUNLIGHT. Hazardous Decomposition Products:NITRIC OXIDE & AMMONIA FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS. UN2672. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.