FISHER SCIENTIFIC -- S347500;SODIUM NITRITE -- 6810-00-241-1140
===================== Product Identification ===================== Product ID:S347500;SODIUM NITRITE MSDS Date:01/07/1995 FSC:6810 NIIN:00-241-1140 === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7523;800-424-9300(CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM NITRITE (CERCLA) CAS:7632-00-0 RTECS #:RA1225000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 85MG/KG (RTECS 94-3) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:**METHEMOGLOBIN FORMER** EYES:MAY CAUSE SEVERE IRRITATION.SKIN:MAY CAUSE IRRITATION.INGEST:TOXIC.MAY CAUSE GI TRACT IRRITATION.INHAL:MAY CAUSE RESPIRATORY IRRITATION. Explanation of Carcinogenicity:SODIUM NITRITE INCREASES THE OCCURANCE OF TUMORS IN THE GI TRACT,LIVER AND LUNGS. Effects of Overexposure:ACUTE EXPOSURE:HYPOTENSION,METHEMOGLOBIN FORMATION WITH CYANOSIS,HEADACHE,DIZZINESS,WEAKNESS,FAINTING.INHAL:SORE THROAT,SHORTNESS OF BREATH.SKIN:DERMATITIS.EYES:CONJUNCTIVITIS.INGEST:NAUSEA,VOMITING,D IARRHEA,ABDOMINAL PAIN,SPINNING HEAD,ELEVATED PULSE,HYPOTENSION. Medical Cond Aggravated by Exposure:MAY CAUSE SENSITIVITY IN PREGNANT WOMEN. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AOR MILD DETERGENT AND WATER.GET MEDICAL ATTENTION.EYES:FLUSH WITH NORMAL SALINE OR WATER FOR 15 MINUTES.GET MEDICAL ATTENTION.INHAL:REMOVE TO FRESH AI R.GIVE OXYGEN OR ARTIFICIAL RESPIRATIONIF NEEDED.KEEP AT REST.INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION.REMOVE BY GASTRIC LAVAGE OR EMESIS. ===================== Fire Fighting Measures ===================== Flash Point:NONE Autoignition Temp:Autoignition Temp Text:1000F Extinguishing Media:WATER ONLY. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT.COOL FIRE EXPOSED CONTAINERS WITH WATER FOG. Unusual Fire/Explosion Hazard:**OXIDIZER** YIELDS OXYGEN UPON COMBUSTION WHICH CAN INCREASE BURNING RATE OF OTHER COMBUSTIBLE MATERIALS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE COMBUSTIBLE MATERIALS.VENTILATE AREA.USE PROPER PROTECTIVE AND RESPIRATORY EQUIPMENT.SWEEP OR SHOVEL;DO NOT CREATE DUST;PLACE IN A DRY CONTAINER.WET SPILLS:ADD CLACIUM HYPOCHLORITE;ADJUST PH TO 7;SOAK UP WITH INERT ABSORBANT.RQ=100LBS. Neutralizing Agent:CALCIUM HYPOCHLORITE(FOR WET SPILLS). ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.KEEP AWAY FROM COMBUSTIBLE MATERIALS AND INCOMPATIBLE MATERIALS. Other Precautions:**OXIDIZER** ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE A TYPE C SUPPLIED AIR RESPIRATOR OPERATED IN THE POSITIVE PRESSURE MODE.FOR FIRE CONDITIONS,ALSO USE AN AUXILLARY SELF-CONTAINED BREATHING APPARATUS EITHER IN PRESSURE DEMAND OR POSITIVE PRESSURE MODE. Ventilation:FUME HOOD. Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:DUST-PROOF GOGGLES Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:EXECISE GOOD LABORATORY PRACTICES.WASH HANDS AFTER USE AND BEFORE EATING. Supplemental Safety and Health SYMPTOMS OF METHEMOGLOBIN FORMATION MAY BE DELAYED FOR A FEW HOURS:CYANOSIS,SEVERE THROBBING HEADACHE ...SHALLOW RESPIRATION,DIZZINESS,CONFUSION,LETHARGY,STUPOR.ABOVE 70%:CONVULSIONS,DEATH(BY CIRCULAT ORY COLLAPSE).ANTIDOTE:1% METHYLENE BLUE AT 0.1ML/KG OVER 10 MINUTES. ================== Physical/Chemical Properties ================== HCC:D2 Boiling Pt:B.P. Text:608F,320C Melt/Freeze Pt:M.P/F.P Text:520F,271C Decomp Temp:Decomp Text:608F,320C Solubility in Water:APPRECIABLE;15% Appearance and Odor:GRANULES/RODS;WHITE TO SLIGHTLY YELLOW.ODOR NOT REPORTED.HYGROSCOPIC. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REDUCING AGENTS. Stability Condition to Avoid:OXIDIZABLE,COMBUSTIBLE OR ORGANIC MATERIALS. Hazardous Decomposition Products:NITROGEN OXIDES AND SODIUM OXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.RCRA CODE IS D001(IGNITABLE). Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.