TEXACO LUBRICANTS CO -- 16389 AUTO-PRO ANTIFREEZE  -- 6850-00N075133
<pre>=====================  Product Identification  =====================

Product ID:16389 AUTO-PRO ANTIFREEZE
MSDS Date:07/02/1996
FSC:6850
NIIN:00N075133
=== Responsible Party ===
Company Name:TEXACO LUBRICANTS CO
Box:4427
City:HOUSTON
State:TX
ZIP:77210-4427
Country:US
Info Phone Num:914-838-7204
Emergency Phone Num:914-831-3400;800-424-9300(CHEMTREC)
CAGE:OTTJ3
=== Contractor Identification ===
Company Name:TEXACO LUBRICANTS
Address:4164 E INNSLAKE DR
Box:4427
City:GLEN ALLEN
State:VA
ZIP:23060
Country:US
Phone:804-527-4311
CAGE:OTTJ3
Company Name:TEXACO PIPELINE INC (SUB OF TEXACO INC)
Address:9700 RICHMOND AVE
Box:42286
City:HOUSTON
State:TX
ZIP:77242-2286
Country:US
Phone:713-953-4260
CAGE:3B431

=============  Composition/Information on Ingredients  =============

Ingred Name:ETHYLENE GLYCOL; (1,2-ETHANEDIOL) (SARA 313) (CERCLA) %:
    80.00-94.99
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: <94.99%
OSHA PEL:N/K 
ACGIH TLV:C 50 PPM, VAPOR
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 3-9.99%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:POTASSIUM PHOSPHATE; DIBASIC; (PHOSPHORIC ACID, DIPOTASSIUM
    SALT)
CAS:7758-11-4
Fraction by Wt: 1-2.99%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SODIUM MONOHYDROGEN PHOSPHATE (2:1:1); (DISODIUM HYDROGEN
    PHOSPHATE) (CERCLA) %: 0.10-0.99
CAS:7558-79-4
RTECS #:WC4500000
Fraction by Wt: <0.99%
OSHA PEL:N/K 
ACGIH TLV:N/K 
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:SODIUM HYDROXIDE (CERCLA)
CAS:1310-73-2
RTECS #:WB4900000
Fraction by Wt: 0.00115%
OSHA PEL:2 MG/M3
ACGIH TLV:C 2 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:VOLATILE ORGANIC COMPOUND: NOT DETERMINED
RTECS #:9999999VO
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SUP DAT: & SEEING, PULM EDEMA, UNCON, CONVLS, COLLAPSE &
    COMA. SYMPS MAY BE DELAYED. DECRD URINE OUTPUT & KIDNEY (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: FAILURE MAY ALSO OCCUR. SEV POIS MAY CAUSE DEATH.
    ASPIR MAY OCCUR DURING SWALLOW/VOMIT RSLTG IN LUNG DMG. (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8: CHRONIC: RPTD INGEST MAY CAUSE KIDNEY DMG. ANIMAL
    TOX DATA: ANIMAL DATA DOES NOT REFLECT HUMAN TOX. ORAL (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9: ADMIN OF ETHYLENE GLYCOL TO PREGNANT EXPT ANIMALS
    HAS CAUSED BIRTH DEFECTS IN OFFSPRING. CONTINUOUS (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10: INGEST OF DIET CONTAINING 1-2% ETHYLENE GLYCOL FOR
    2 YRS PRDCED LIVER & KIDNEY DMG & BLADDER STONES IN RATS.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC: ANYTHING BY MOUTH TO AN UNCON/CONVL PERS.
    INHAL: REMOVE TO FRESH AIR. GET MED ATTN IF BRTHG (ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12: BECOMES DFCLT/RESP IRRIT PERSISTS. ETHYLENE GLYCOL
    (EG) & DIETHYLENE GLYCOL (DEG) INTOX MAY INITIALLY (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13: PRDCE BEHAVIORAL CHANGES, DROW, VOMIT, DIARR,
    THIRST, & CONVLS. EG & DEG ARE NAPHROTOX. END STAGES OF (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14: POIS MAY INCL RENAL DMG/FAILURE W/ACIDOSIS.
    SUPPORTIVE MEASURES, SUPP W/HEMODIALYSIS IF INDICATED, MAY (ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15: LIM PROGRESSION & SEV OF TOX EFTS. FOR EG POIS
    INTRAVENOUS ETHANOL IS A RECOGNIZED ANTIDOTAL TREATMENT: (ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16: OTHER ANTIDOTAL TREATMENTS ALSO EXIST FOR EG POIS.
    FOR DEG POIS ROLE OF INTRAVENOUS ETHANOL IN (ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17: TREATMENT IS UNCLEAR BUT MAY BE OF BENEFIT IN VIEW
    OF STRUCTURAL & TOX SIMILARITIES TO EG. CONT POIS CTR(ING 19)
RTECS #:9999999ZZ

Ingred Name:ING 18: FOR FURTHER TREATMENT INFO. ASPIR DURING INDUCED
    EMESIS MAY RSLT IN SEV LUNG INJURY. IF EVACUATION OF (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19: STOM IS NEC, USE METH LEAST LIKELY TO CAUSE ASPIR,
    SUCH AS GASTRIC LAVAGE AFTER ENDOTRACHEAL INTUBATION.(ING 21)
RTECS #:9999999ZZ

Ingred Name:ING 20: CONTACT A POISON CENTER FOR ADDITIONAL TREATMENT
    INFORMATION.
RTECS #:9999999ZZ

Ingred Name:WASTE DISP METH: INTO STORM SEWERS. DISP OF I/A/W LOC,
    STATE & FED REGS . FOR MORE SPECIFIC INFO CONT NEHC .
RTECS #:9999999ZZ

Ingred Name:OTHER PREC: SYS/OTHER SYS WHERE CONTAM OF POTABLE WATER
    SUPP IS POSS. FOR MORE SPECIFIC INFO CONT NEHC .
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE:MAY CAUSE IRRIT W/MILD
    DISCOMFORT & SLIGHT EXCESS REDNESS. SKIN:BRIEF CONT MAY CAUSE LIGHT
    IRRIT. PRLNG CONT, AS W/CLTHG WETTED W/MATL, MAY CAUSE MORE SEV
    IRRIT & DISCOMFORT W/REDNESS & SWEL L. OTHER EFTS NOT EXPECTED.
    INHAL:VAP/MIST, IN EXCESS OF PERMISSIBLE CONCS/IN UNUSUALLY HIGH
    CONCS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:GENERATED FROM SPRAYING, HEATING
    MATL/AS FROM EXPOS IN POORLY VENTD AREAS/CONFINED SPACES, MAY CAUSE
    IRRIT OF NOSE & THROAT, HDCH, NAUS & DROW. PRLNG/RPTD OVEREXP MAY
    RSLT IN ABSORPTION OF PO TENTIALLY HARMFUL AMTS.
    INGEST:ETHYLENEGLYCOL & DIETHYLENE GLYCOL TOX IF SWALLOWED. LETHAL
    DOSE FOR ADULT IS (SUP DAT)
Medical Cond Aggravated by Exposure:REPEATED OVEREXPOSURE MAY AGGRAVATE
    EXISTING KIDNEY DISEASE. BECAUSE OF ITS IRRITATING PROPERTIES,
    REPEATED SKIN CONTACT MAY AGGRAVATE AN EXISTING DERMATITIS (SKIN
    CONDITION).

=======================  First Aid Measures  =======================

First Aid:EYE: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN. HOLD
    EYELIDS APART WHILE FLUSHING TO RINSE ENTIRE SURF OF EYE & LIDS
    W/WATER. GET MED ATTN. SKIN: WASH W/PLENTY OF SOAP & WATER FOR
    SEVERAL MIN.  GET MED ATTN IF IRRIT DEVELOPS/PERSISTS. INGEST: IF
    CONSCIOUS & ABLE TO SWALLOW, IMMED GIVE 2 GLASSES (16 OZ) OF WATER.
    INDUCE VOMIT AS DIRECTED BY MED PERS. GET IMMED MED ATTN. NEVER
    GIVE (ING 12)

=====================  Fire Fighting Measures  =====================

Flash Point Method:CC
Flash Point:244F,118C
Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL, FOAM, OR CARBON
    DIOXIDE TO EXTINGUISH FLAMES.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . USE
    WATER SPRAY TO COOL FIRE-EXPOSED CONTRS. WATER/FOAM MAY CAUSE
    FROTHING. APPROACH FIRE FROM UPWIND (SUP DAT)
Unusual Fire/Explosion Hazard:NONE.

==================  Accidental Release Measures  ==================

Spill Release Procedures:VENT AREA. AVOID BRTHG VAP. WEAR APPROP PERS
    PROT EQUIP, INCL APPROP RESP PROT. CONTAIN SPILL IF POSS. WIPE
    UP/ABSORB ON SUITABLE MATL & SHOVEL UP. PVNT ENTRY INTO SEWERS &
    WATERWAYS. FOR MORE SPECIFI C INFO CONT NEHC .
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:MINIMUM FEASIBLE HNDLG TEMPS SHOULD BE
    MAINTAINED. PERIODS OF EXPOS TO HIGH TEMPS SHOULD BE MINIMIZED.
    WATER CONTAMINATION SHOULD BE AVOIDED.
Other Precautions:ACUTE/CHRONIC CONSUMPTION OF PRODS CONTAINING
    ETHYLENE GLYCOL CAN PRDCE SIGNIFICANT ADVERSE HLTH EFTS, INCL
    DEATH, IN HUMANS & ANIMALS. KEEP OUT OF REACH OF CHILDREN & PETS.
    SUCH PRODS SHOULD NOT BE U SED IN POTABLE (DRINKING) WATER (ING 23)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:AIRBORNE CONCS SHOULD BE KEPT TO LOWEST LEVELS
    POSS. IF VAP, MIST/DUST IS GENERATED & OCCUP EXPOS LIM OF PROD/ANY
    COMPONENT OF PROD, IS EXCEEDED, USE APPROP NIOSH APPRVD AIR
    PURIFYING/AIR SUPP RESP. F OR MORE SPECIFIC INFO CONT NEHC .
Ventilation:ADEQUATE TO MEET COMPONENT OCCUPATIONAL EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
    ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH EXPOSED SKIN SEVERAL TIMES DAILY W/SOAP &
    WATER. SOILED WORK CLTHG SHOULD BE LAUNDERED/DRY-CLEANED.
Supplemental Safety and Health
FIRE FIGHT PROC:TO AVOID HAZ VAPS & TOX DECOMP PRODS. HAZ DECOMP
    PROD:MAY PRDCE IRRIT ALDEHYDES, ACIDS & KETONES. EFTS OF
    OVEREXP:1-2 ML/KG/ABOUT 4 OZ (HALF-CUP). SYMPS INCL HDCH, WEAK,
    CONFUSN, DIZZ,  STAG, SLURRED SPEECH, LOSS OF COORD, FAINTNESS,
    NAUS & VOMIT, INCRD HEART RATE, DECRD BLOOD PRESS, DFCLTY BRTHG
    (ING 7)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:388F,198C
Vapor Pres:<0.1
Vapor Density:2.1
Spec Gravity:1.13 (H*2O=1)
pH:11
Solubility in Water:>10%
Appearance and Odor:FLUORESCENT GREEN LIQUID, MILD ODOR

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOX LEVELS OF CARBON MONOXIDE &
    DIOXIDE, IRRIT ALDEHYDES & KETONES MAY BE FORMED ON BURNING.
    HEATING IN AIR (SUP DAT)

====================  Disposal Considerations  ====================

Waste Disposal Methods:TO PVNT CONTAM OF DRINKING WATER SUPPLIES, &
    POIS OF CHILDREN, AQUATIC LIFE, WILDLIFE, & FARM & DOMESTIC
    ANIMALS, ETHYLENE GLYCOL PRODS SUCH AS USED ANTIFREEZE SOLN,
    REGARDLESS OF QTY, SHOULD NEVER BE	DISCARDED ONTO GROUND, INTO
    SURF WATER/ (ING 22)

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