PHILLIPS PETROLEUM CO, PHILLIPS 66 CO DIV -- GASOLINES (ALL GRADES) -- 9130-01-135-2507
===================== Product Identification ===================== Product ID:GASOLINES (ALL GRADES) MSDS Date:03/31/1990 FSC:9130 NIIN:01-135-2507 === Responsible Party === Company Name:PHILLIPS PETROLEUM CO, PHILLIPS 66 CO DIV Address:699 ADAMS BLDG City:BARTLESVILLE State:OK ZIP:74004 Country:US Info Phone Num:918-661-8327, 918-661-5952 Emergency Phone Num:918-661-3865, 918-661-8118 CAGE:46916 === Contractor Identification === Company Name:PHILLIPS 66 COMPANY(DIVISION OF PHILLIPS PETROLEUM CO) Address:699 ADAMS BLDG 411 KEELER ST Box:City:BARTLESVILLE State:OK ZIP:74004 Country:US Phone:918-661-8327 CAGE:6Y142 Company Name:PHILLIPS PETROLEUM CO Address:613 ADAMS Box:City:BARTLESVILLE State:OK ZIP:74004 Country:US Phone:800-234-6603 CAGE:46935 Company Name:PHILLIPS PETROLEUM COMPANY CAGE:46916 ============= Composition/Information on Ingredients ============= Ingred Name:GASOLINE. THE INGEDIENTS FOLLOWING MAKE-UP THE GASOLINE. CAS:8006-61-9 RTECS #:LX3300000 Fraction by Wt: 100% Other REC Limits:NONE SPECIFIED OSHA PEL:300 PPM/500 STEL ACGIH TLV:300 PPM/500STEL,9293 Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: <5% Other REC Limits:NONE SPECIFIED OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: <10% Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL BENZENE (SARA III) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: <2% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/125 STEL ACGIH TLV:100 PPM/125STEL 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:P-XYLENE (P-DIMETHYLBENZENE) (SARA III) CAS:106-42-3 RTECS #:ZE2625000 Fraction by Wt: <3% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:M-XYLENE (M-DIMETHYLBENZENE) (SARA III) CAS:108-38-3 RTECS #:ZE2275000 Fraction by Wt: <6% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/15OSTEL;9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:O-XYLENE (O-DIMETHYLBENZENE) (SARA III) CAS:95-47-6 RTECS #:ZE2450000 Fraction by Wt: <3% Other REC Limits:NONE SPECIFIED OSHA PEL:100PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHYL-TERT-BUTYL ETHER (SARA III) CAS:1634-04-4 RTECS #:KN5250000 Fraction by Wt: <15% Other REC Limits:NONE SPECIFIED EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:1,2,4-TRIMETHYL BENZENE (SARA III) CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: <3% Other REC Limits:NONE SPECIFIED OSHA PEL:25 PPM ACGIH TLV:25 PPM; 9293 Ingred Name:TETRAETHYL LEAD (SARA III) (< 0.25 G/GAL, EQUIVALENT TO <0.1 G PB/GAL FOR LEADED GASOLINE; <0.05 G PB/GAL FOR UNLEADED. CAS:78-00-2 RTECS #:TP4550000 Fraction by Wt: <.25%G/G Other REC Limits:NONE SPECIFIED OSHA PEL:S, 0.075 MG PB/M3 ACGIH TLV:S, 0.1 MG PB/M3 9293 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 ORAL RAT IS UNKNOWN. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:EYES: MAY CAUSE SLIGHT IRRITATION. SKIN: SLIGHT IRRITATION. INHALATION: MAY CAUSE HEADACHE, NAUSEA, WEAKNESS, SEDATION, AND UNCONSCIOUSNESS. INGESTION: MAY CAUSE IRRITATION TO INTESTINES. MAY BE ASPIR ATED INTO LUNGS IF SWALLOWED, WHICH MAYRESULT IN PULMONARY EDEMA AND CHEMICAL PNEUMONITIS. Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION. INHALATION: HEADACHE, NAUSEA, WEAKNESS, SEDATION, AND UNCONSCIOUSNESS. INGESTION: IRRITATION TO INTESTINES. ASPIRATION INTO LUNG AFTER INGESTION MAY RESULT IN PULMO NARY EDEMA AND CHEMICAL PNEUMONITIS. Medical Cond Aggravated by Exposure:PERSON WITH PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN OR RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE TO THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. IF IRRITATION DEVELOPS GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AREA WITH SOAP AND WATER. IF IRRITATION DEVELOPS GET MEDICAL ATTENTION. INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING GIVE CPR. IF BREATHING DIFFICULT GIVE OXYGEN. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:<-37.2C, -35.F Lower Limits:1.5 Upper Limits:7.6 Extinguishing Media:DRY CHEMICALS, FOAM, CARBON DIOXIDE. Fire Fighting Procedures:DO NOT SPRAY WATER DIRECTLY ON FIRE, PRODUCT WILL FLOAT AND REIGNITE ON WATER SURFACE. WATER FOG OR SPRAY MAY BE USED TO COOL EXPOSED CONTAINERS AND EQUIPMENT. Unusual Fire/Explosion Hazard:HIGHLY FLAMMABLE VAPORS WHICH ARE HEAVIER THAN AIR MAY ACCUMULATE IN LOW AREAS AND SPREAD ALONG GROUND TO DISTANT IGNITION SOURCE AND FLASHBACK. ================== Accidental Release Measures ================== Spill Release Procedures:SHUT OFF SOURCE IF POSSIBLE. VENTILATE AREA. PROTECT FROM IGNITION. DIKE AREA TO CONTAIN SPILL. KEEP OUT OF WATER SOURCES AND SEWERS.. ABSORB IN DRY, INERT MATERIAL. TRANSFER TO DISPOSAL CONTAINERS US ING NON-SPARKING TOOLS. WEAR PROTECTIVEEQUIPMENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED AREA AWAY FROM HEAT, IGNITION SOURCES, INCOMPATIBLE MATERIALS. KEEP CONTAINERS CLOSED WHEN NOT IN USE. Other Precautions:PROTECT CONTAINERS FROM PHYSICAL DAMAGE. BOND AND GROUND CONTAINERS DURING TRANSFER. DO NOT SIPHON BY MOUTH. PROVIDE MEANS OF CONTROLLING LEAKS AND SPILLS. AVOID CONTACT WITH EYES AND AVOID BREATHING VAPORS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR FOR CONCENTRATIONS EXCEEDING THE RECOMMENDED EXPOSURE LEVEL. WHEN ENTRY INTO CONCENTRATIONS OF UNKNOWN EXPOSURE, USE NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS (SCBA). Ventilation:USE ADEQUATE VENTILATION TO CONTROL EXPOSURE BELOW RECOMMENDED LEVELS. USE EXPLOSION-PROOF EQUIPMENT. Protective Gloves:VITON, NITRILE, PVA. Eye Protection:SAFETY GLASSES WITH SIDE SHIELDS. Other Protective Equipment:FULL BODY LONG-SLEEVED GARMENTS TO PREVENT REPEATED OR PROLONGED SKIN CONTACT. EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.. Supplemental Safety and Health PERSONAL PROTECTION INFORMATION SHOWN ABOVE IS BASED UPON GENERAL INFORMATION AS TO NORMAL USES AND CONDITIONS. WHERE SPECIAL OR UNUSUAL CONDITIONS EXIST, IT IS SUGGESTED THAT THE EXPERT ASSISTANCE OF AN INDUSTRIAL HYGIENIST OR OTHER QUALIFIED PROFESSIONAL BE SOUGHT. ================== Physical/Chemical Properties ================== HCC:F1 Boiling Pt:=26.7C, 80.F Vapor Pres:350-800 Vapor Density:3-4 Spec Gravity:0.8 Evaporation Rate & Reference:>1 (BUTYL ACETATE = 1) Solubility in Water:NEGLIGIBLE Appearance and Odor:RED-ORANGE LIQUID. PUNGENT ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXYGEN AND STRONG OXIDIZING AGENTS. Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:CARBON OXIDES, LEAD FUMES (FOR GRADES CONTAINING TETRAETHYL LEAD), AND VARIOUS HYDROCARBONS WHEN BURNED. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT YOUR LOCAL ENVIRONMENTAL OFFICER. DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.