MALLINCKRODT BAKER INC -- CALCIUM OXIDE, 1410 -- -
===================== Product Identification ===================== Product ID:CALCIUM OXIDE, 1410 MSDS Date:12/08/1996 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:MALLINCKRODT BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2151;800-424-9300 Resp. Party Other MSDS Num.:C0462 Chemtrec Ind/Phone:(800)424-9300 CAGE:70829 === Contractor Identification === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:CALCIUM OXIDE CAS:1305-78-8 RTECS #:EW3100000 = Wt:100. OSHA PEL:5 MG/M3 ACGIH TLV:2 MG/M3 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: INHALATION OF DUST IS HIGHLY IRRITATING AND POSSIBLY CORROSIVE TO UPPER RESPIRATORY TRACT. MAY CAUSE COUGHING, SNEEZING, LABORED BREATHING, AND POSSIBLY BURNS WITH PERFORATION OF TH E NASAL SEPTUM. INGESTION: CORROSIVE. MAY ATTACK THE ESOPHAGUS. ABDOMINAL PAIN, NAUSEA, VOMITING MAY RESULT. MAY CAUSE SERIOUS ALKALI BURNS IN MOUTH AND THROAT. SKIN CONTACT: IRRITANT; MAY CAUSE SEVER E CORROSIVE DAMAGE. EYE CONTACT: SEVERE IRRITANT, MAY DAMAGE EYE TISSUES. CAUSES REDNESS, TEARING, BLURRED VISION, PAIN. CHRONIC: CHRONIC INHALATION OF DUST MAY CAUSE INFLAMMATION OF (EFTS OF OVEREXP) Effects of Overexposure:HLTH HAZS: THE RESPIRATORY PASSAGES, ULCERS OF THE MUCOUS MEMBRANES, AND POSSIBLE PERFORATION OF NASAL SEPTUM. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN DISORDERS OR EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL PHYSICIAN. INGEST: DO NOT INDUCE VOMITING! GIVE LARGE QUANTITIES OF WATER OR MIL K IF AVAILABLE. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. GET MEDICAL ATTENTION IMMEDIATELY. SKIN CONT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMD CLOTHING & SHOES. CALL PHYSICIAN, IMMEDIATELY. WASH CLTHG BEFORE REUSE. EYE CONT: WASH THOROUGHLY W/RUNNING WATER FOR AT LST 15 MINS. GET MEDICAL ADVISE IF IRRITATION DEVELOPS. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:IN EVENT OF FIRE, WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE HAZARD. LIME & WATER CAN REACT EXOTHERMICALLY W/SUFFICIENT HEAT TO IGNITE COMBUSTIBLE MATLS IN CERTAIN INSTANCES. NOT CONSIDERED TO BE AN EXPLOSION HAZARD. THE COMBINATION OF LIME AND WATER AT HIGH TEMPERATURES MAY BE EXPLOSIVE. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. KEEP UNNECESSARY & UNPROTECTED PEOPLE AWAY FROM AREA OF SPILL. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT AS SPECIFIED IN EXPOSURE CONTROLS/PERSONAL PROT. SPILLS: PICK UP & PLACE IN SUITABLE CONTAINER FOR RECLAMATION OR DISPOSAL, USING A METHOD THAT DOES NOT GENERATE DUST. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP TIGHTLY CLOSED CONTAINER. PROTECT FROM PHYSCIAL DAMAGE. STORE IN A COOL, DRY, VENTILATED AREA AWAY FROM SOURCES OF HEAT, MOISTURE & INCOMPATIBILITIES. Other Precautions:THIS STRONGLY ALKALINE MATL WILL SWELL & GENERATE HEAT WHEN MOISTENED & COULD BURST CNTNR. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (DUST, SOLIDS); OB SERVE ALL WARNINGS & PRECAUTIONS LISTED FOR THE PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOS LIMIT IS EXCEEDED, NIOSH APPRVD FULL FACEPIECE RESP W/ DUST/MIST FILTER MAY BE WORN UP TO 50 TIMES EXPOS LIMIT/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP SUPPLIER, WHICHEVER IS L OWEST. FOR EMER/INSTANCES WHERE EXPOS LEVELS ARE NOT KNOWN, USE NIOSH APPRVD FULL-FACEPIECE POS-PRESS, AIR-SUPPLIED RESP. WARNING: NIOSH APPRVD AIR (SUPDAT) Ventilation:SYS OF LOC AND/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIMITS. LOC EXHST VENT IS GENERALLY PREF BECAUSE IT CAN CTL EMISSIONS(SUPDAT) Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPRVD CHEMICAL WORKERS GOGGLES & FULL LENGTH FACESHIELD . Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . WEAR IMPERVIOUS PROT CLOTHING, INCLUDING BOOTS, LAB COAT, APRON OR COVERALLS, AS APPROP, TO PREVENT SKIN CONT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health RESP PROT: PURIFYING RESPS DO NOT PROTECT WORKERS IN OXYG-DEFICIENT ATM. VENT: OF CONTAMINANT @ ITS SOURCE. PVNTG DISPERSION OF IT INTO GEN WORK AREA. PLEASE REFER TO ACGIH DOCUMENT, INDUS VENT, MANUA L OF REC PRACTICES, MOST RECENT EDITION, FOR DETAILS. PH: 12.5 SATURATED SOLN IN WATER. ================== Physical/Chemical Properties ================== Boiling Pt:=2850.C, 5162.F Melt/Freeze Pt:=2572.2C, ######F Vapor Density:1.9(AIR=1) Spec Gravity:3.37 pH:SUPDAT Solubility in Water:OTHER INFO Appearance and Odor:WHITE TO SLIGHTLY YELLOWISH POWDER. ODORLESS. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, ACIDS, HUMID AIR, HYDROGEN FLUORIDE, PHOSPHOROUS PENTOXIDE, BORIC OXIDE, STEAM, MANY ORGANIC SUBSTANCES. Stability Condition to Avoid:AIR, MOISTURE, AND INCOMPATIBLES. STABLE AT ROOM TEMPERATURE IN SEALED CONTAINERS. Hazardous Decomposition Products:NO HAZARDOUS DECOMPOSITION PRODUCTS. ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL TOXICITY: THIS MATERIAL IS EXPECTED TO BE TOXIC TO AQUATIC LIFE. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING SHOULD BE MANAGED IN APPROP & APPRVD WASTE DISP FACILITY. PROCESSING, USE/CONTAM OF THIS PROD MAY CHANGE WASTE MANAGEMENT OPTIONS. STATE & LOCAL DISP RE GS MAY DIFFER FROM FED DISP REGS. DISPOSE OF CNTNR & UNUSED CONTENTS I/A/W FEDERAL, STATE & LOCAL RE QUIREMENTS. =================== MSDS Transport Information =================== Transport Information:NOT REGULATED. ===================== Regulatory Information ===================== SARA Title III Information:CHEMICAL WEAPONS CONVENTION: NO. TSCA 12(B): NO. CDTA: NO. SARA 311/312: ACUTE: YES. CHRONIC: YES. FIRE: NO. PRESSURE: NO REACTIVITY: YES. (PURE/SOLID). Federal Regulatory Information:CHEM INVENTORY STATUS - PART 1. INGRED: CALCIUM OXIDE (1305-78-8) TSCA-YES, EC-YES, JAPAN-YES, AUSTRALIA-YES. CHEM INVENTORY STATUS - PART 2. INGRED: CALCIUM OXIDE 91305-78-8) --CANADA-- KOREA-YES, DS L-YES, NDSL-NO, PHIL.-YES. FED, STATE & INTERNATIONAL REGS - PART 1. INGRED CALCIUM OXIDE (1305-78-8)- -SARA 302: RQ-NO, TPQ-NO. --SARA 313---LIST-NO, CHEM CATGL-NO. FED, STATE & INTERNATIONAL REGS - PART 2: INGRED CALCIUM OXIDE (1305-78-8): CERCLA-NO. RCRA 261.33-NO, TSCA 8(D)-NO. AUSTRALIAN HAZCHE M CODE. NO INFO FOUND. POISON SCHEDULE: NO INFO FOUND. State Regulatory Information:OTHER INFO: DO NOT BREATHE DUST. KEEP CONTAINER CLOSED. USE ONLY W/ADEQ VENT. WASH THOROUGHLY AFTER HANDLING. LABEL FIRST AID: IN CASE OF CONT, IMMED FLUSH EYES/SKIN W/PLENTY OF WATER FOR AT LST 15 MI NS. REMOVE CONTAMD CLTHG & SHOES. WASH CLTHG BEFORE REUSE. IF SWALLOWED, DO NOT INDUCE VOMIT. GIVE LG QTYS OF WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. IF INHALED, REMOVE TO FRESH AIR. IF N OT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. IN ALL CASES CALL PHYS. PROD USE: LABORATO RY REGENT. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.