WILLIAM MARVY COMPANY, INC. -- MAR-V-CIDE -- -
===================== Product Identification ===================== Product ID:MAR-V-CIDE MSDS Date:07/01/1987 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:WILLIAM MARVY COMPANY, INC. Address:1540 ST. CLAIR AVE. City:ST. PAUL State:MN ZIP:55105 Country:US Info Phone Num:612-698-0726/800-874-2651 Emergency Phone Num:612-454-6113/612-457-3293 Preparer's Name:ROBERT MARVY, SECRETARY Chemtrec Ind/Phone:(800)424-9300 CAGE:3S962 === Contractor Identification === Company Name:WILLIAM MARVY COMPANY, INC. Address:1540 ST. CLAIR AVE. Box:City:ST. PAUL State:MN ZIP:55105 Country:US Phone:612-698-0726/800-874-2651 CAGE:3S962 ============= Composition/Information on Ingredients ============= Ingred Name:HYAMINE 3500. (N-ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE) [CN H2N+1-N(CH3)2-CH2C6H5]+ CL-) (ROHM & HAAS CODE: 707-63) (NO MFR CAS# PROVIDED) CAS:68424-85-1 RTECS #:UZ2995000 = Wt:50. Ingred Name:ISOPROPYL ALCOHOL. (ISOPROPANOL; 2-PROPANOL; DIMETHYL CARBINOL: IPA) (C3 H8 0) (MCKESSON CODE: TL238010) CAS:67-63-0 RTECS #:NT8050000 Ingred Name:SODIUM NITRITE. (NITROUS ACID; SODIUM SALT) (NA N O2) (VW&R CODE: T1174) CAS:7632-00-0 RTECS #:RA1225000 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:TRITON X-100 SURFACTANT. (AN OCTYLPHENOXX-POLYETHOXYETHANOL NONIONIC SULFACTANT) (VW&R CODE: T1336) CAS:9036-19-5 RTECS #:MD0907600 Ingred Name:WATER. (NO MFR CAS# PROVIDED) CAS:7732-18-5 RTECS #:ZC0110000 Ingred Name:DYE. (NO MFR CAS# PROVIDED) ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:THE EYE IS LISTED AS A ROUTE OF ENTRY. INHALATION: INHALATION OF MIST & VAPORS MAY IRRITATE THE RESPIRATORY TRACT. LARGE AMOUNTS MAY CAUSE SYSTEMATIC EFFECTS. EYE CONTACT: VAPORS WILL IRRITATE THE EYE S. LIQUID & MIST CAN SEVERELY IRRITATE OR DAMAGE THE EYES & CAUSE CORNEAL BURNS. SKIN CONTACT: BRIEF CONTACT MAY DRY SKIN, OR CAUSE BURNING OR STINGING SENSATION. PROLONGED OR REPEATED CONTACT MAY IRR ITATE SKIN, CAUSING DERMATITIS. INGESTION: SWALLOWING LARGE QUANTITIES CAN CAUSE HEADACHES, NAUSEA, VOMITING, STOMACH CRAMPS AND DIARRHEA, & PERHAPS UNCONSCIOUSNESS, OR DEATH. CHRONIC EFFECTS OF EXPOS URE: NO SPECIFIC INFORMATION AVAILABLE. Effects of Overexposure:REFER TO HEALTH HAZARDS ACUTE AND CHRONIC. FIRST AID (CONT'D): IF VOMITING OCCURS SPONTANEOUSLY, KEEP VICTIM'S HEAD BELOW THE HIPS TO PREVENT BREATHING THE VOMITUS INTO THE LUNGS. Medical Cond Aggravated by Exposure:NONE REPORTED. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET IMMEDIATE MEDICAL ATTENTION. EYE CONTACT: IMMEDIATELY FLUSH EYES WITH LOTS OF RUNNING WATER FOR 30 MINUTES, LIFTING T HE UPPER AND LOWER EYELIDS OCCASIONALLY. GET IMMEDIATE MEDICAL ATTENTION. SKIN CONTACT: IMMEDIATELY WASH SKIN WITH LOTS OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION IF IRRITATION PERSISTS AFTER WASHING. INGESTION: DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE PINT OF LUKEWARM WATER. GET IMMEDIATE MEDICAL ATTENTION. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS O R CONVULSING PERSON. (SIGNS & SYMPTOMS) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL OR CO2. Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. USE WATER SPRAY TO COOL NEARBY CONTAINERS AND STRUCTURES EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:NONE CURRENTLY KNOWN. NONFLAMMABLE, NONVOLATILE, ODORLESS, NONCORROSIVE, NONIRRITATING IN USE DILUTION. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT INCLUDING RUBBER BOOTS, RUBBER GLOVES, RUBBER APRON, AND A NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS IN THE PRESSURE DEMAND MODE OR SUPPLIED-AIR RESPIRATOR. IF THE S PILL OR LEAK IS SMALL, A NIOSH APPROVED FULL FACE-PIECE AIR-PURIFYING CARTRIDGE RESPIRATOR EQUIPPED WITH PARTICULATE FILTERS MAY BE SATISFACTORY. IN ANY EVENT, ALWAYS WEAR EYE PROTECTION. (TRANSPORT) ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, WELL-VENTILATED DRY PLACE. STORE AWAY FROM ALL OTHER CHEMICALS AND POTENTIAL SOURCES OF CONTAMINATION. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. DO NOT USE PRESSURE TO EMPTY CONT AINER. WASH THOROUGHLY AFTER HANDLING. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. Other Precautions:CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, WILL RETAIN PRODUCT RESIDUE. ALWAYS OBEY CONTAINER WARNINGS AND HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL. REPAIR AND MAINTENANCE PRECAUTIONS: NONE CU RRENTLY KNOWN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR IN THE ABSENCE OF ADEQUATE ENVIRONMENTAL CONTROL AT POINT OF USE. Ventilation:LOCAL MECHANICAL EXHAUST VENTILATION CAPABLE OF MAINTAINING EMISSIONS AT THE POINT OF USE BELOW THE PEL. Protective Gloves:RUBBER GLOVES. Eye Protection:ANSI APPROVED CHEMICAL GOGGLES. IT IS GENERALLY RECOGNIZED THAT (SUPP DATA) Other Protective Equipment:AN EYE WASH AND SAFETY SHOWER MEETING ANSI DESIGN CRITERIA SHOULD BE NEARBY AND READY FOR USE. LONG-SLEEVED SHIRT, TROUSERS, SAFETY SHOES, AND RUBBER APRON. Work Hygienic Practices:WASH CONTAMINATED CLOTHING AND SHOES BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health EYE PROTECTION (CONT'D): CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH CHEMICALS BECAUSE CONTACT LENSES MAY CONTRIBUTE TO THE SEVERITY OF ANY EYE INJURY. ================== Physical/Chemical Properties ================== Boiling Pt:=96.1C, 205.F B.P. Text:205 - 575 F. Melt/Freeze Pt:=52.8C, 127.F M.P/F.P Text:127 - 538 F. Vapor Pres:MM HG/20 C: NIL. Vapor Density:>2.1 AIR=1 Spec Gravity:2.17 (WATER=1). Evaporation Rate & Reference:3 (BUTYL ACETATE-1). Solubility in Water:100%. Appearance and Odor:BLUE-GREEN-BLACK----LIGHT BLUE LIQUID. MEDICINAL ALCOHOLIC. ALMOST NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS. Stability Condition to Avoid:EXCESSIVE HEAT. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:ORAL: RAT: LD50 5840 MG/KG. DERMAL: RABBIT: LD50 >3000 MG/KG. INHALATION: RAT: LC50 1.45 MG/L4HR. THE INGREDIENTS LISTED FOR THIS MATERIAL, IN THEIR RAW UN-MIXED OR UN-DILUTED STATE, HAVE CAUSED PERM ANENT CORNEAL DAMAGE IN RABBITS WHEN APPLIED IN CONCENTRATIONS GREATER THAN 10%. SODIUM NITRATE HAS BEEN FOUND AS AN ANIMAL MUTAGENIC AND TUMORIGENIC AGENT. EXPOSURE LIMITS, PPM: CONCENTRATE TO DILUTI ON: 20 - < 99; OSHA-PEL: 400 - NONE; ACGIH - TLV: 400 - NONE. OTHER LIMIT: NONE. HAZARD = FLAMMABLE, IRRITANT, AND OXIDIZER-----NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS . DISPOSE OF CONTAMINATED PRODUCT & MATERIALS USED IN CLEANING UP SPILL/LEAKS IN A MANNER APPROVED FOR TH IS MAT ERIAL. NOTE: EMPTY CONTAINERS CAN HAVE RESIDUE, GASSES AND MISTS AND ARE SUBJECT TO PROPER WASTE DIS POSAL. =================== MSDS Transport Information =================== Transport Information:N/P. SPILL/RELEASE (CONT'D): FOR SMALL SPILLS, SWEEP UP AND DISPOSE OF IN DOT APPROVED WASTE CONTAINERS. FOR LARGE SPILLS, SHOVEL INTO DOT APPROVED WASTE CONTAINERS. KEEP OUT OF SEWERS, STORM DRAINS, SURFACE WATERS, AND SOIL. COMPLY WITH ALL APPLICABLE GOVERNMENTAL REGULATIONS ON SPILL REPORTING, AND HANDLING AND DISPOSAL OF WASTE. ===================== Regulatory Information ===================== State Regulatory Information:N/P. OTHER INFORMATION (CONT'D): THE FINISHED PRODUCT AS SOLD IS FURTHER DILUTED FOR NORMAL USEAGE IN THE FOLLOWING MANNER: THE LABEL INDICATES THAT THE USER IS TO MAKE A SOLUTION OF THIS PRODUCT CONT AINING 2 OZ. OF MAR-V-CIDE AND 126 OZ. OF WATER TO MAKE A GALLON OF "SHOP STRENGTH" SOLUTION. DO KEEP IN MIND MSDS GIVES INFORMATION RELATIVE FROM A HIGH CONCENTRATE TO A DILUTED FORM. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.