HARRIS WELCO -- ER70S6 -- 3439-01-343-3854
===================== Product Identification ===================== Product ID:ER70S6 MSDS Date:12/04/1996 FSC:3439 NIIN:01-343-3854 === Responsible Party === Company Name:HARRIS WELCO Address:1051 YORK RD City:KINGS MOUNTAIN State:NC ZIP:28086 Country:US Info Phone Num:704-739-6421 Emergency Phone Num:704-739-6421;800-424-9300(CHEMTREC) CAGE:HO911 === Contractor Identification === Company Name:HARRIS WELCO Address:1051 YORK RD Box:City:KINGS MOUNTAIN State:NC ZIP:28086 Country:US Phone:704-739-6421 CAGE:HO911 Company Name:J. W. HARRIS CO INC & HARRIS WELCO, DIVISION/J.W. HARRIS CO Address:1051 YORK RD Box:City:KINGS MOUNTAIN State:NC ZIP:28086 Country:US Phone:704-739-6421 CAGE:34920 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON BLACK; (CARBON) CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: >0.50% OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 Ingred Name:MANGANESE (SARA 313) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: >2.50% OSHA PEL:5 MG/M3 DUST, C ACGIH TLV:5 MG/M3 DUST Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: >1.50% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:COPPER (SARA 313) (CERCLA) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: >0.50% OSHA PEL:0.1MG/M3 FUME;1 DUST ACGIH TLV:0.2 MG/M3 FUME EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:MOLYBDENUM CAS:7439-98-7 RTECS #:QA4680000 Fraction by Wt: >0.75% OSHA PEL:10 PPM ACGIH TLV:10 PPM Ingred Name:ALUMINUM (SARA 313) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: >0.50% OSHA PEL:15 MG/M3 DUST ACGIH TLV:10 MG/M3 DUST Ingred Name:TITANIUM CAS:7440-32-6 RTECS #:XR1700000 Fraction by Wt: >0.50% Ingred Name:ZIRCONIUM CAS:7440-67-7 RTECS #:ZH7070000 Fraction by Wt: >0.50% OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3; 10 STEL Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: BALANCE Ingred Name:SUPDAT: IN PERCENT & FORM FROM INGREDS LISTED IN INGRED SECTION. FUME & GAS DECOMP PRODS & NOT INGREDS IN (ING 11) Ingred Name:ING 10: ELECTRODE, ARE IMPORTANT. CONC OF GIVEN FUME OR GAS COMPONENT MAY DECREASE OR INCREASE BY MANY TIMES (ING 12) Ingred Name:ING 11: ORIGINAL CONCENTRATION IN ELECTRODE. NEW COMPOUNDS NOT IN ELECTRODE MAY FORM. DECOMP PRODS OF NORMAL (ING 13) Ingred Name:ING 12: OPERATION INCLUDE THOSE ORIGINATING FROM VOLATILIZATION, REACTION, OXIDATION OF MATLS IN INGRED SECTION (ING 14) Ingred Name:ING 13: PLUS THOSE FROM BASE METAL & COATING. REASONABLY EXPECTED FUME CONSTITUENTS OF PROD COULD INCLUDE (ING 15) Ingred Name:ING 14: PRIMARILY OXIDES OF IRON; SECONDARILY COMPLEX OXIDES OF MANGANESE & SILICON & ALUMINUM. GASEOUS REACTION(ING 16) Ingred Name:ING 15: PRODS - CARBON MONOXIDE, CARBON DIOXIDE. OZONE & NITROGEN OXIDES MAY BE FORMED BY RADIATION FROM ARC & (ING 17) Ingred Name:ING 16: SHIELDING GASES WHEN EMPLOYED. ONE RECOMD WAY TO DETERMINE COMPOSITION & QTY OF FUMES & GASES TO WHICH (ING 18) Ingred Name:ING 17: WORKERS ARE EXPOSED IS TO TAKE AIR SAMPLE FROM INSIDE WELDERS HELMET OR IN WORKING ZONE. SEE AWS F1.1 & (ING 19) Ingred Name:ING 18: AWS F1.2-1985, AVAIL FROM AMERICAN WELDING SOCIETY. SEE AWS PUBLICATION: "FUMES & GASES IN WELDING ENVIRONMENT." Ingred Name:OTHER PROT EQUIP: SEE ANSI Z49.1-1893, SAFETY IN WELDING & CUTTING, WELDING HANDBOOK, VOL 1, SAFE PRACTICES IN (ING 21) Ingred Name:ING 20: WELDING & CUTTING. ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO Health Hazards Acute and Chronic:ELECTRIC ARC WELDING MAY CREATE THE FOLLOWING: FUMES AND GASES CAN BE DANGEROUS TO YOUR HEALTH. ARC RAYS CAN INJURE EYES AND BURN SKIN. ELECTRIC SHOCK CAN KILL. SHORT TERM EXPOSURE: DIZZINESS, NAUSEA, DRYNESS AND IRRITATION OF NOSE, THROAT, EYES, CHEST TIGHTNESS, FEVER, ALLERGIC REACTION; OVEREXPOSURE (EFTS OF OVEREXP) Explanation of Carcinogenicity:CARBON BLACK: IARC MONOGRAPHS, VOL 65, PG 149, 1996:GROUP 2B. Effects of Overexposure:HLTH HAZ: TO FUMES: SIDEROSIS POSSIBLE, MAY AFFECT PULMONARY FUNCTION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST: CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) . EYES: IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD . SKIN: FLUSHW/COPIOUS AMOUNTS OF WATER. CALL MD . REMOVE TO FRESH AIR, OBTAIN MEDICAL ATTENTION. EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY AMERICAN RED CROSS. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WELDING ARC & SPARKS CAN IGNITE COMBUSTS & FLAMMABLES. REFER TO ANSI Z49.1 FOR FIRE PREVENTION DURING (SUDPAT) Unusual Fire/Explosion Hazard:NOT APPLICABLE. ================== Accidental Release Measures ================== Spill Release Procedures:NOT APPLICABLE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:NOT APPLICABLE. Other Precautions:NOT APPLICABLE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . MAKE SURE INHALED AIR DOES NOT CONTAIN FUME CONSTITUENTS ABOVE PERMISSIBLE EXPOSURE LEVELS. Ventilation:MAKE SURE INHALED AIR DOES NOT CONTAIN FUME CONSITUENTS ABOVE PERMISSIBLE EXPOSURE LEVELS. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . OTHER PRECAUTIONS FOR ADDNL SAFETY INFO ON WELDING & CUTTING, (ING 20) Work Hygienic Practices:FOR MAXIMUM SAFETY, BE CERTIFIED FOR AND WEAR A NIOSH APPROVED RESPIRATOR AT ALL TIMES WHEN WELDING OR BRAZING. Supplemental Safety and Health FIRE FIGHT PROC: USE OF WELDING & ALLIED PROCEDURES. HAZ DECOMP PRODS: USED. OTHER FACTORS INCL COATINGS ON METAL BEING WELDED (PAINT, PLATING OR GALVANIZING), NUMBER OF WELDERS & VOL OF WORK AREA AS PRESENCE OF CONTAMINANTS IN ATM. WHEN ELECTRODE IS CONSUMED FUME & GAS DECOMP PRODS GENERATED ARE DIFFERENT (ING 10) ================== Physical/Chemical Properties ================== Appearance and Odor:SOLID WIRE OR ROD. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:COMPOSITION & QUALITY OF WELDING FUMES & GASES ARE DEPENDENT UPON METAL BEING WELDED, PROCESS & ELECTRODE BEING (SUPDAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD PRODUCT RESIDUE, DISPOSABLE CONTAINER OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER IN FULL COMPLIANCE WITH FEDERAL, STATE AND LOCA L REGULATIONS. ====================================================================== Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.