MALLINCKRODT BAKER INC -- STANNOUS CHLORIDE, 3986 -- 6810-00-300-5152
===================== Product Identification ===================== Product ID:STANNOUS CHLORIDE, 3986 MSDS Date:04/15/1998 FSC:6810 NIIN:00-300-5152 === Responsible Party === Company Name:MALLINCKRODT BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2151;800-424-9300(CHEMTREC) CAGE:HO851 === Contractor Identification === Company Name:MALLINCKRODT BAKER INC Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:HO851 Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:STANNOUS CHLORIDE, SOLID (ANHYDROUS). LD50:(ORAL,RAT) 700 MG/KG. CAS:7772-99-8 RTECS #:XP8700000 Fraction by Wt: 98-100% OSHA PEL:2 MG/M3 (SN) ACGIH TLV:2 MG/M3 (SN) Ingred Name:CNDTNS (STAB):PRESENT IN AQ SOLNS. ABSORBS OXYG FROM AIR & FORMS INSOL OXYCHLORIDE. FORMS AN INSOL BASIC SALT (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:WHEN DISSOLVED W/MUCH WATER. RTECS #:9999999ZZ Ingred Name:MATLS TO AVOID:W/HYDRAZINE HYDRATE TO FORM DIHYDRAZINE CHLORIDE, WHICH DECOMPOSES EXPLOSIVELY WHEN HEATED. CONT (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:W/STRONG OXIDIZING AGENTS OR ALKALIS WILL GENERATE HEAT & FUMES. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:INFO:ANHYDROUS:INVESTIGATED AS A TUMORIGEN, MUTAGEN, REPRO EFFECTOR. HYDRATE:INVESTIGATED AS A (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6:MUTAGEN, REPRODUCTIVE EFFECTOR. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:OF WATER FOR AT LEAST 15 MINUTES, LIFTING LOWER & UPPER LIDS OCCASIONALLY. GET MED ATTN IMMEDIATELY. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH:CONTAINER & UNUSED CONTENTS I/A/W FEDERAL, STATE & LOCAL REQUIREMENTS. RTECS #:9999999ZZ Ingred Name:RESP PROT:WHERE EXPOS LEVELS ARE NOT KNOWN, USE A NIOSH APPRVD FULL-FACEPIECE POS-PRESS, AIR-SUPPLIED RESP. (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:WARNING:AIR PURIFYING RESPIRATORS DO NOT PROTECT WORKERS IN OXYGEN-DEFICIENT ATMOSPHERES. RTECS #:9999999ZZ Ingred Name:VENT:GENERALLY PREFERRED BECAUSE IT CAN CONTROL EMISSIONS OF CONTAM AT ITS SOURCE, PREVENTING DISPERSION OF IT (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:INTO GEN WORK AREA. PLEASE REFER TO ACGIH DOCUMENT, "INDUSTRIAL VENTILATION, A MANUAL OF RECOMMENDED (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:PRACTICES", MOST RECENT EDITION, FOR DETAILS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:CAUSES IRRIT TO RESP TRACT. SYMPS MAY INCL COUGH, SHORTNESS OF BREATH. INGEST:CAUSES IRRIT TO GI TRACT. SYMPS MAY INCL NAUS, VOMIT & DIARR. MAY CAUSE BURNING IN MOUTH & THROAT, ABDOM PAIN, REDUCED BLOOD PRESS, STOM BLEEDING, COLLAPSE & CONVLS. MAY CAUSE LIVER & KIDNEY DMG. SKIN CONT:CAUSES (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:IRRIT. SYMPS INCL REDNESS, ITCH & PAIN. EYE CONT:CAUSES IRRIT, REDNESS & PAIN. CHRONIC:RPTD SKIN CONT W/SOLNS MAY CAUSE SKIN RASHES IN SUSCEPTIBLE INDIVIDUALS. PRLNG INHAL OF DUST/FUME MAY RS LT IN BENIGN PNEUMOCONIOSIS, PRDCG DISTINCTIVE CHANGES IN LUNGS W/NO APPARENT DISABILITY/COMPLICATIONS. TOX (ING 6) Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN DISORDERS OR EYE PROBLEMS, OR IMPAIRED LIVER, KIDNEY OR RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG. GET MED ATTN. INGEST:INDUCE VOMIT IMMED AS DIRECTED BY MED PERS. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS. GET MED ATTN. SKIN:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS. REMOVE CONTAM CLTHG & SHOES. GET MED ATTN. WASH CLTHG BEFORE REUSE. THORO CLEAN SHOES BEFORE REUSE. EYES:IMMED FLUSH W/PLENTY (ING 8) ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . AQ SOLNS OF THIS MATL ARE ACIDIC. AVOID ITS CONT W/EYES & SKIN. AVOID BRTHG ITS FUMES/DUST. WHEN HEATED (SUPDAT) Unusual Fire/Explosion Hazard:NO CONSIDERED TO BE FIRE HAZ. NOT CONSIDERED EXPLO HAZ, BUT REACTS EXPLOSIVELY WHEN MIXED W/NITRATES OR HYDROGEN PEROXIDE (>3% SOLN). SEALED CNTNRS MAY (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR APPROPRIATE PERSONAL PROT EQUIP AS SPECIFIED IN EXPOSURE CONTROLS/PERSONAL PROTECTION SECTION. SWEEP UP & CONTAINERIZE FOR RECLAMATION OR DISPOSAL. VACUUMING OR W ET SWEEPING MAY BE USED TO AVOID DUST DISPERSAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:GEN STORAGE. KEEP IN TIGHTLY CLSD CNTNR, STORED IN COOL, DRY, VENTED AREA. PROT AGAINST PHYSICAL DMG. ISOLATE FROM INCOMPAT SUBSTANCES. CORR SOLID. Other Precautions:HARMFUL IF SWALLOWED/INHALED. AVOID CONT W/EYES, SKIN & CLTHG. AVOID BRTHG DUST. USE ONLY W/ADEQ VENT. AQ SOLNS ARE ACIDIC; USE ONLY IN CORR-RESIST VESSELS. CNTNRS OF THIS MATL MAY BE HAZ WHEN EMPTY S INCE THEY RETAIN PROD RESIDUES (SUPDAT) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOS LIM IS EXCEEDED, NIOSH APPRVD FULL FACEPIECE RESP WITH DUST/MIST FILTER MAY BE WORN UP TO 50 TIMES EXPOS LIM/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP SUPPLIER, WHICHEVER IS LOW EST. FOR EMERGENCIES/INSTANCES (ING 10) Ventilation:VENT HOOD. SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IS (ING 12) Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT) Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER . WEAR IMPERVIOUS PROT CLTHG, INCL BOOTS, LAB COAT, APRON/ (SUPDAT) Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health MP:100F,38C (WHEN RAPIDLY HEATED). FIRE FIGHT PROC:TO DECOMP IT EMITS TOX & CORR FUME OF HYDROCHLORIC ACID. EXPLO HAZ:RUPTURE WHEN HEATED. OTHER PREC:(DUST, SOLIDS); OBSERVE ALL WARNINGS & PRECS LISTE D FOR PROD. EYE PROT:& FULL LENGTH FACESHIELD . OTHER PROT EQUIP:COVERALLS, AS APPROP, TO PREVENT SKIN CONTACT. ================== Physical/Chemical Properties ================== Melt/Freeze Pt:M.P/F.P Text:SUPP DATA Spec Gravity:2.71 Solubility in Water:118G/100ML @ 0C,32F. Appearance and Odor:COLORLESS CRYSTALS; SLIGHT ODOR OF HYDROCHLORIC ACID. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SODIUM, POTASSIUM, BROMINE TRIFLUORIDE, CALCIUM CARBIDE, CALCIUM ACETYLIDE, ETHYLENE OXIDE & NITRATES. REACTS (ING 4) Stability Condition to Avoid:MOISTURE, HEAT, FLAMES, IGNIT SOURCES & INCOMPATS. POWERFUL REDUCING AGENT. SM QTYS OF HYDROCHLORIC ACID ARE (ING 2) Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION IT EMITS TOXIC & CORROSIVE FUME OF HYDROCHLORIC ACID. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING SHOULD BE MANAGED IN APPROP & APPRVD WASTE DISP FACILITY. PROCESSING, USE/CONTAM OF THIS PROD MAY CHANGE WASTE MANAGMENT OPTIONS. STATE & LOC DISP REGS MAY DIFFER FROM FED DISP REGS. DISP OF (ING 9) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.