VALVOLINE CO -- MACS TIRE SHINE 4200  -- 8010-00N073722
<pre>=====================  Product Identification  =====================

Product ID:MACS TIRE SHINE 4200
MSDS Date:02/10/1995
FSC:8010
NIIN:00N073722
=== Responsible Party ===
Company Name:VALVOLINE CO
Box:14000
City:LEXINGTON
State:KY
ZIP:40512
Country:US
Info Phone Num:606-357-7847
Emergency Phone Num:800-274-5263
CAGE:IO754
=== Contractor Identification ===
Company Name:THE VALVOLINE CO
Box:14000
City:LEXINGTON
State:KY
ZIP:40512
Country:US
Phone:606-357-7847
CAGE:IO754
Company Name:VALVOLINE OIL CO
Address:3499 BLAZER PKY
Box:14000
City:LEXINGTON
State:KY
ZIP:40512
Country:US
Phone:606-357-7206 / 800-274-5263
CAGE:72527

=============  Composition/Information on Ingredients  =============

Ingred Name:HEPTANE
CAS:142-82-5
RTECS #:MI7700000
Fraction by Wt: 73-83%
OSHA PEL:500 PPM
ACGIH TLV:400 PPM/500 STEL

Ingred Name:POLYPROPYLENE GLYCOL
CAS:25322-69-4
RTECS #:TR5250000
Fraction by Wt: 7-17%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:GAS OIL, BLEND; (ALIPHATIC PETROLEUM DISTILLATES)
CAS:64741-44-2
RTECS #:LX3296000
Fraction by Wt: 2.8-13%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:CARBON DIOXIDE
CAS:124-38-9
RTECS #:FF6400000
Fraction by Wt: 1-7%
OSHA PEL:5000 PPM
ACGIH TLV:5000PPM/30000STEL

Ingred Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 2.4%
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:SUP DAT: (OR ITS COMPONENTS) HAS BEEN SUGGESTED AS A CAUSE
    OF THE FOLLOWING EFTS IN HUMANS, & MAY AGGRAVATE (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6: PREEXISTING DISORDERS OF THESE ORGANS: CNS EFTS.
    CHRONIC: TOLUENE APPEARS ON THE NAVY LISTING OF OCCUP (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: CHEMICAL REPRODUCTIVE HAZARDS. SEEK CONSULTATION
    FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNING LATEST (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8: HAZARD LIST INFORMATION AND SAFE HANDLING AND
    EXPOSURE INFORMATION .
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC: DOWN. SEEK MED ATTN. IF POSS, DO NOT LEAVE
    INDIVIDUAL UNATTENDED. INHAL: IMMED MOVE INDIVIDUAL (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10: AWAY FROM EXPOS & INTO FRESH AIR. SEEK IMMED MED
    ATTN; KEEP PERS WARM & QUIET. IF PERS IS NOT BRTHG, (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11: BEGIN ARTIFICIAL RESPIRATION. IF BREATHING IS
    DIFFICULT, ADMINISTER OXYGEN.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC: COMPLETED. STOP SPILL AT SOURCE. PVNT FROM
    ENTERING DRAINS, SEWERS, STREAMS/OTHER BODIES OF WATER. (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13: PVNT FROM SPREADING. IF RUNOFF OCCURS, NOTIFY AUTH
    AS REQUIRED. PUMP/VACUUM TRANSFER SPILLED PROD TO (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14: CLEAN CONTRS FOR RECOVERY. ABSORB UNRECOVERABLE
    PROD. TRANSFER CONTAM ABSORB, SOIL & OTHER MATLS TO (ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15: CONTRS FOR DISP. PVNT RUN-OFF TO SEWERS,
    STREAMS/OTHER BODIES OF WATER. IF RUN-OFF OCCURS, NOTIFY (ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16: PROPER AUTHORITIES AS REQUIRED, THAT A SPILL HAS
    OCCURRED.
RTECS #:9999999ZZ

Ingred Name:RESP PROT: SPECIFIED CONDITIONS (CONSULT YOUR INDUSTRIAL
    HYGIENIST). ENGINEERING OR ADMINISTRATIVE CONTROLS (ING 19)
RTECS #:9999999ZZ

Ingred Name:ING 18: SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: MAY CAUSE MILD IRRIT.
    SYMPS MAY INCL STINGING, TEARING, & REDNESS. SKIN: MAY CAUSE MILD
    IRRIT. PRLNG/RPTD EXPOS MAY DRY SKIN. SYMPS MAY INCL REDNESS,
    BURNING, DRYING & CRACKING, & SKIN BUR NS. INGEST: SINGLE DOSE ORAL
    TOX IS LOW. SWALLOWING SML AMTS DURING NORM HNDLG IS NOT LIKELY TO
    CAUSE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: HARMFUL EFTS; SWALLOWING LGE AMTS MAY
    BE HARMFUL. THIS MATL CAN ENTER LUNGS DURING SWALLOWING/VOMIT &
    CAUSE LUNG INFLAMM &/DMG. INHAL: EXPOS TO VAP/MIST IS POSS.
    SHORT-TERM INHAL TOX IS LOW.  BRTHG SML AMTS DURING NORM HNDLG IS
    NOT LIKELY TO CAUSE HARMFUL EFTS; BRTHG LGE AMTS MAY BE HARMFUL.
    SYMPS OF (SUP DAT)
Medical Cond Aggravated by Exposure:PREEXISTING SKIN DISORDERS MAY BE
    AGGRAVATED BY EXPOS TO THIS MATL. PREEXISTING LUNG DISORDERS (E.G.,
    ASTHMA-LIKE CNDTNS) MAY BE AGGRAVATED BY EXPOS TO THIS MATL.

=======================  First Aid Measures  =======================

First Aid:EYE: IMMED MOVE INDIVIDUAL AWAY FROM EXPOS & INTO FRESH AIR.
    FLUSH EYES GENTLY W/WATER FOR AT LEAST 15 MIN WHILE HOLDING EYELIDS
    APART; SEEK IMMED MED ATTN. SKIN: REMOVE CONTAM CLTHG. WASH EXPOSED
    ARE A W/SOAP & WATER. IF SYMPS PERSIST, SEEK MED ATTN. LAUNDER
    CLTHG BEFORE REUSE. INGEST: DO NOT INDUCE VOMIT. THIS MATL IS AN
    ASPIR HAZ. IF INDIVIDUAL IS DROWSY/UNCON, PLACE ON LEFT SIDE W/HEAD
    (ING 10)

=====================  Fire Fighting Measures  =====================

Flash Point Method:TCC
Flash Point:15.0F,-9.4C
Lower Limits:1%
Extinguishing Media:REGULAR FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP .
    WATER MAY BE USED TO KEEP FIRE-EXPOSED CONTRS COOL UNTIL FIRE IS
    OUT. REFER TO PERS PROT EQUIP SECTION OF MSDS.
Unusual Fire/Explosion Hazard:MATL IS HIGHLY VOLAT & READILY GIVES OFF
    VAPS WHICH MAY TRAVEL ALONG GROUND/BE MOVED BY VENT & IGNITED BY
    PILOT LIGHTS, OTHER FLAMES, SPKS, HEATERS, (SUP DAT)

==================  Accidental Release Measures  ==================

Spill Release Procedures:SML SPILL: ABSORB LIQ ON VERMICULITE, FLOOR
    ABSORB/OTHER ABSORB MATL. LGE SPILL: ELIM ALL IGNIT SOURCES
    (FLARES, FLAMES INCL PILOT LIGHTS, ELEC SPKS). PERS NOT WEARING
    PROT EQUIP SHOULD BE EXCLUDED FR OM AREA OF SPILL UNTIL CLEAN-UP
    HAS BEEN (ING 13)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:CONTRS OF THIS MATL MAY BE HAZ WHEN
    EMPTIED. SINCE EMPTIED CONTRS RETAIN PROD RESIDUES(VAP, LIQ
    &/SOLID), ALL HAZ PREC GIVEN IN MSDS MUST BE OBSERVED.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF WORKPLACE EXPOS LIM OF PROD/ANY COMPONENT IS
    EXCEEDED (SEE EXPOS GUIDELINES), A NIOSH APPRVD AIR SUPPLIED RESP
    IS ADVISED IN ABSENCE OF PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT
    OTHER NIOSH APPRVD	RESPS (NEG PRESS TYPE) UNDER (ING 18)
Ventilation:PROVIDE SUFFICIENT MECHENICAL (GENERAL AND/OR LOCAL
    EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:NITRILE RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
    ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: SMKNG, ELEC MOTORS, STATIC DISCHARGE/OTHER IGNIT SOURCES AT
    LOCATIONS DISTANT FROM MATL HNDLG POINT. EFTS OF OVEREXP: EXPOS: GI
    IRRIT (NAUS, VOMIT, DIARR), IRRIT (NOSE, THROAT, RESP TRACT),  CNS
    DEPRESS (DIZZ, DROW, WEAK, FATG, NAUS, HDCH, UNCON), & DEATH.
    TARGET ORGAN EFTS: OVEREXP TO THIS MATL (ING 6)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:200F,93C
Vapor Pres:40 @ 68F
Vapor Density:>1
Spec Gravity:0.750
Evaporation Rate &amp; Reference:SLOWER THAN ETHYL ETHER
Appearance and Odor:CLEAR, COLORLESS LIQUID
Percent Volatiles by Volume:85-100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM CARBON DIOXIDE AND CARBON
    MONOXIDE, VARIOUS HYDROCARBONS.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
    LOCAL, STATE AND FEDERAL REGULATIONS.

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