CIBA-GEIGY CORP, AGRICULTURAL DIV. -- PRAMITOL 25E -- 6840-00-145-0013
===================== Product Identification ===================== Product ID:PRAMITOL 25E MSDS Date:04/10/1995 FSC:6840 NIIN:00-145-0013 Status Code:A === Responsible Party === Company Name:CIBA-GEIGY CORP, AGRICULTURAL DIV. Address:410 SWING ROAD Box:18300 City:GREENSBORO State:NC ZIP:27419 Country:US Info Phone Num:800-888-8372 Emergency Phone Num:800-888-8372 Chemtrec Ind/Phone:(800)424-9300 CAGE:8K340 === Contractor Identification === Company Name:CIBA-GEIGY CORP, AGRICULTURAL DIV. Address:410 SWING ROAD Box:18300 City:GREENSBORO State:NC ZIP:27419 Phone:800-888-8372 OR 800-334-9481 CAGE:8K340 Company Name:EHRLICH J C CHEMICAL CO INC Address:500 SPRING RIDGE DR Box:City:READING State:PA ZIP:19612-3848 Country:US Phone:610-372-9700/FAX: 610-378-9744 CAGE:8C885 ============= Composition/Information on Ingredients ============= Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 = Wt:10. Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYL BENZENES (SARA 313) CAS:100-41-4 RTECS #:DA0700000 = Wt:2. Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/125STEL;9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:N-BUTYL ALCOHOL (SARA 313) (CERCLA) CAS:71-36-3 RTECS #:EO1400000 = Wt:10. Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:S, C 50 PPM; 9596 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:PRIMATOL (PROMETON) CAS:1610-18-0 RTECS #:XY4200000 Other REC Limits:NONE RECOMMENDED Ingred Name:TRIMETHYLBENZENES = Wt:13. Ingred Name:PETROLEUM SOLVENT ACGIH TLV:525 MGF/M3 Ingred Name:PHENYL GLYCOL ETHER SOLVENT = Wt:10. ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 2100MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EXPOSURE CAN CAUSE IRREVERSIBLE EYE DAMAGE & SEVERE SKIN IRRITATION. IF SWALLOWED, ABDOMINAL PAIN, NAUSEA, VOMITING, GASTRITIS WEAKNESS, HEADACHE OR DIARRHEA CAN OCCUR. PROLONGED INHALATION EXPOSURE C AN CAUSE RESPIRATORY TRACT IRRITATION & CNS DEPRESSION. THE PETROLEUM SOLVENT CAN CAUSE A CHEMICAL PNEUMONIA IF ASPIRATED. CHRONIC: PRODUCT DOES NOT CAUSE CANCER OR OTHER LONG-TERM EFFECTS. ADDITIONAL LY, PRODUCT DOES NOT AFFECT REPRODUCTIVE CAPABILITIES OVER 2 RAT GENERATIONS AND WAS NEGATIVE FOR MUTAGENIC POTENTIAL. Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER'S MSDS. Effects of Overexposure:EXPOSURE CAN CAUSE IRREVERSIBLE EYE DAMAGE & SEVERE SKIN IRRITATION. IF SWALLOWED, ABDOMINAL PAIN, NAUSEA, VOMITING, GASTRITIS WEAKNESS, HEADACHE OR DIARRHEA CAN OCCUR. PROLONGED INHALATION EXPOSURE C AN CAUSE RESPIRATORY TRACT IRRITATION, HEADACHE, DROWSINESS. THE PETROLEUM SOLVENT CAN CAUSE A CHEMICAL PNEUMONIA IF ASPIRATED. Medical Cond Aggravated by Exposure:PERSONS WITH CHRONIC RESPIRATORY DISORDERS OR PRE-EXISTING DERMATITIS SHOULD USE EXTRA CARE IN HANDLING THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:INGESTED-DO NOT INDUCE VOMITING! IF CONSCIOUS, GIVE LOTS OF WATER TO DRINK. APPLY ARTIFICIAL RESPIRATION IF NEEDED. EYES-IMMEDIATELY RINSE WITH LOTS OF RUNNING WATER, LIFTING LIDS. DO NOT APPLY MEDICA TING AGENTS UNLESS DIRECTED BY A PHYSICIAN. SKIN-WASH WITH PLENTY OF SOAP & WATER. DO NOT APPLY MEDICATING AGENTS UNLESS DIRECTED BY A PHYSICIAN. REMOVE CONTAMINATED CLOTHES & WASH BEFORE REUSE. INHAL ED-MOVE VICTIM FROM CONTAMINATED AREA TO FRESH AIR. APPLY ARTIFICIAL RESPIRATION IF NEEDED. ===================== Fire Fighting Measures ===================== Flash Point:=34.4C, 94.F Autoignition Temp:=171.1C, 340.F Lower Limits:1.3 Upper Limits:4.9 Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE, FOAM. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. EVACUATE NON-ESSENTIAL PERSONNEL. PREVENT USE OF CONTAMINATED BUILDINGS, AREA AND EQUIPMENT UNTIL DECONTAMINATED. Unusual Fire/Explosion Hazard:THIS ITEM FORMS FLAMMABLE MIXTURES ABOVE 77F. BURNING CAN PRODUCE CARBON MONOXIDE OR CARBON DIOXIDE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROPER PROTECTIVE CLOTHING. COVER SPILL WITH ABSORBENT MATERIAL SUCH AS SWEEPING COMPOUND OR KITTY LITTER. SWEEP UP AND PLACE IN AN APPROVED CHEMICAL CONTAINER. WASH AREA WITH WATER & STRONG DETE RGENT. ABSORB LIQUID WITH KITTY LITTER AND PLACE INA CHEMICAL CONTAINER. SEAL CONTAINER AND HANDLE IN AN APPROVED MANNER. DO NOT ALLOW WASH WATER TO CONTAMINATE WATER SUPPLIES. Neutralizing Agent:NOT APPLICABLE. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED SECURE PLACE OUT OF REACH OF CHILDREN & DOMESTIC ANIMALS. PREVENT EATING, DRINKING, TOBACCO USAGE AND COSMETIC APPLICATION IN AREAS WHERE THERE IS A POTENTIAL FOR E XPOSURE TO THE MATERIAL. ALWAYS WASH THOROUGHLY AFTER HANDLING. Other Precautions:FOLLOW LABEL DIRECTIONS. AVOID BREATHING VAPORS. AVOID SKIN AND EYE CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:TO AVOID BREATHING MISTS OR SPRAYS, WEAR A NIOSH-APPROVED FULL FACEMASK CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE AND PESTICIDE PRE-FILTER. Ventilation:NONE SPECIFIED BY MANUFACTURER'S MSDS. Protective Gloves:RUBBER. Eye Protection:CHEMICAL SPLASH GOGGLES OR FULL FACE SHIELD. Other Protective Equipment:RUBBER BOOTS, LONG SLEEVED SHIRT, LONG PANTS AND HEAD COVERING. PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:ALWAYS WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health EPA REG #100-517.THE TARGET ORGAN FOR PROMETON IS THE LIVER.NOTE TO PHYSICIAN: INDUCTION OF EMESIS IS NOT RECOMMENDED DUE TO THE PRESENCE OF THE PETROLEUM SOLVENT. CHECK FOR MUCOSAL DAMAGE BEFORE PERF OMING GASTRIC LAVAGE. REMAINING TOXICANT CAN BE ADSORBED WITH ACTIVATED CHARCOAL. NO SPECIFIC ANTIDOTE IF INGESTED. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:=122.C, 251.6F Vapor Pres:3 MM HG @ 20C Spec Gravity:0.935 Evaporation Rate & Reference:NOT AVAILABLE Solubility in Water:SLIGHT(PROMETON) Appearance and Odor:YELLOW TO AMBER LIQUID; AROMATIC SOLVENT ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS Hazardous Decomposition Products:NONE KNOWN. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:PRAMITOL 25E CONTAINS AN AROMATIC SOLVENT COMPOSED OF ETHYLBENZENE AND AROMATIC NAPHTHA CONTAINING TRIMETHYLBENZENES. INHALATION OF SOLVENT VAPORS AT HIGH CONCENTRATIONS CAN CAUSE CENTRAL NERVOUS SYST EM DEPRESSION, RESPIRATORY TRACT IRRITATION, ASPHYXIATION, CARDIAC STRESS AND COMA. EXPOSURE TO EXTREMELY HIGH LEVELS OF XYLENES CAN CAUSE KIDNEY OR LIVER DAMAGE. BUTANOL IS MODERATLEY TOXIX BY INGEST ION, IRRITATING THE SKIN AND SEVERELY IRRITATING TO THE EYES. PROLONGED EXPOSURE TO HIGH CONCENTRATIONS OF VAPORS MAY CAUSE HEADACHE, DIZZINESS, DROWSINESS & NAUSEA. LONG-TERM OVEREXPOSURE MAY CAUSE L OSS OF HEARING. ===================== Ecological Information ===================== Ecological:NONE SPECIFIED BY MANUAFCTURER'S MSDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT REUSE PRODUCT CONTAINERS. DISPOSE OF PRODUCT CONTAINERS, WASTE CONTAINERS, AND RESIDUES ACCORDING TO LOCAL, STATE AND FEDERAL HEALTH AND ENVIRONMENTAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:DOT CLASSIFICATION: COMPOUNDS, TREE OR WEED KILLING, LIQUID (XYLENE), CLASS 3, NA1993 PGIII. ===================== Regulatory Information ===================== SARA Title III Information:ACUTE AND CHRONIC HEALTH HAZARD, FIRE HAZARD. SECTION 313 CHEMICALS: ETHYLBENZENE (CAS 100-41-4); N-BUTANOL (CAS 71-36-3); M-XYLENE (CAS 108-38-3); O-XYLENE (CAS 95-47-6); 1,2,4-TRIMETHYLBENZENE (CAS 95-63-6) AND PHENYL GLYCOL ETHER (CAS 122-98-8) Federal Regulatory Information:RQ BASED ON BUTANOL CONTENT: 5400 GALLONS. BASED ON XYLENE CONTENT: 1280 GALLONS. RCRA CLASSIFICATION: FLAMMABLE. State Regulatory Information:CALIFORNIA PROPOSITION 65: NOT DETERMINED. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.