EASTMAN KODAK COMPANY -- 169 1757,PT A,BLEACH BATH,KODAK SEPIA TONER -- 6750-00-110-8067
===================== Product Identification ===================== Product ID:169 1757,PT A,BLEACH BATH,KODAK SEPIA TONER MSDS Date:02/28/2000 FSC:6750 NIIN:00-110-8067 Status Code:A Kit Part:Y === Responsible Party === Company Name:EASTMAN KODAK COMPANY Address:343 STATE STREET City:ROCHESTER State:NY ZIP:14650 Country:US Info Phone Num:716-722-5151/(800) 242-2424 Emergency Phone Num:716 722-5151 Preparer's Name:NOT PROVIDED CAGE:19139 === Contractor Identification === Company Name:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS Address:343 STATE ST Box:City:ROCHESTER State:NY ZIP:14650-1115 Country:US Phone:716-722-5151/(800) 242-2424 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM BROMIDE CAS:7758-02-3 RTECS #:TS7650000 Minumum % Wt:45. Maxumum % Wt:55. Ingred Name:POTASSIUM FERRICYANIDE CAS:13746-66-2 RTECS #:LJ8225000 Minumum % Wt:45. Maxumum % Wt:55. ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD-50 (RAT): 0.5-5.0 G/KG Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. IF CYANIDE GAS IS LIBERATED DUE TO CONTACT WITH A STRONG ACID, IT MAY CAUSE DIZZINESS, HEADACHE, RAPID RESPIRATIO N, RAPID PULSE, UNCONSIOUSNESS, CONVULSIONS AND DEATH. EYES: NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN: LOW HAZARD FOR RECOMMENDED HANDLING. INGESTION: HARMFUL IF SWALLOWED. INGE STION OF BROMIDE SALTS CAN CAUSE NAUSEA, VOMITING, HEADACHE, IRRITABILITY, DELIRIUM, MEMORY LOSS, DECREASED APPETITE, JOINT PAIN, HALLUCINATIONS, STUPOR, COMA, AND ACNELIKE RASH ON FACE, LEGS, AND TRU NK. Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION (COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NON E - NATIONAL TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE Effects of Overexposure:INHALATION: IF CYANIDE GAS IS LIBERATED DUE TO CONTACT WITH A STRONG ACID, IT MAY CAUSE DIZZINESS, HEADACHE, RAPID RESPIRATION, RAPID PULSE, UNCONSIOUSNESS, CONVULSIONS AND DEATH. EYES: MAY CAUSE TRAN SIENT IRRITATION. INGESTION: INGESTION OF BROMIDE SALTS CAN CAUSE NAUSEA, VOMITING, HEADACHE, IRRITABILITY, DELIRIUM, MEMORY LOSS, DECREASED APPETITE, JOINT PAIN, HALLUCINATIONS, STUPOR, COMA, AND ACN ELIKE RASH ON FACE, LEGS, AND TRUNK. Medical Cond Aggravated by Exposure:NOT PROVIDED ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: ANY MATERIAL THAT CONTACTS THE EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. GET MEDICAL ATTENTION I F SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: ONLY INDUCE VOMITING AT THE INSTRUCTION OF MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN U NCONSCIOUS PERSON. GET MEDICAL ATTENTION IMMEDIATELY. ===================== Fire Fighting Measures ===================== Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:POWDERED MATERIAL MAY FORM EXPLOSIVE DUST-AIR MIXTURES. FIRE OR HIGH TEMPERATURES MAY CAUSE DECOMPOSITION. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT UP AND PUT IN A SUITABLE CONTAINER. AVOID GENERATION OF DUST. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NOT RELEVANT ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP AWAY FROM HEAT. POWDERED MATERIAL MAY FORM EXPLOSIVE DUST-AIR MIXTURES. MINIMIZE DUST GENERATION AND ACCUMULATION. USE WITH ADEQUATE VENTILATION. KEEP AWAY FROM SOURCES OF IGNITION. KEEP FROM CONTACT WITH OXIDIZING MATERIALS Other Precautions:AVOID PROLONGED OR REPEATED BREATHING OF DUST. AVOID CONTACT WITH EYES AND PROLONGED OR REPEATED CONTACT WITH SKIN. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. A FULL-FACE POSITIVE-PRESSURE AIR-SUPPLIED RESPIRATOR MUST BE WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE RELEASED OR HAVE BEEN RELEASED. SEE STABILITY AND REACTIV ITY SECTION. IF RESPIRATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING APPROPRIATE FOR RISK OF EXPOSURE Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES). Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE EYE CONTACT. Supplemental Safety and Health USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE LEVEL. ABBREVIATION: N/A=NOT APPLICABLE OR NOT AVAILABLE. N/K=UNKNOWN. N/P =NOT PROVIDED. N/R=NOT RELEVANT. N/D=NOT DETERMINED. N/E=NOT ESTABLISHED. ================== Physical/Chemical Properties ================== HCC:B1 NRC/State Lic Num:NOT RELEVANT Melt/Freeze Pt:M.P/F.P Text:DECOMPOSES Decomp Temp:=305.C, 581.F Vapor Pres:NEGLIGIBLE Spec Gravity:NOT AVAILABLE Solubility in Water:APPRECIABLE Appearance and Odor:ORANGE SOLID (CRYSTAL). ODOR: ODORLESS Percent Volatiles by Volume:NEGLIGIBLE Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS. CONTACT WITH ACID LIBERATES FLAMMABLE MATERIAL, TOXIC GAS. Stability Condition to Avoid:STABLE. MATERIALS CONTAINING SIMILAR STRUCTURAL GROUPS CAN DECOMPOSE IF HEATED ABOVE 310C (590F). Hazardous Decomposition Products:CYANIDES, HYDROGEN BROMIDE. CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN. =================== Toxicological Information =================== Toxicological Information:EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. IF CYANIDE GAS IS LIBERATED DUE TO CONTACT WITH A STRONG ACID, IT MAY CAUSE DIZZINESS, HEADACHE, RAPID RESPIRATIO N, RAPID PULSE, UNCONSIOUSNESS, CONVULSIONS AND DEATH. EYES: NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN: LOW HAZARD FOR RECOMMENDED HANDLING. INGESTION: HARMFUL IF SWALLOWED. INGES TION OF BROMIDE SALTS CAN CAUSE NAUSEA, VOMITING, HEADACHE, IRRITABILITY, DELIRIUM, MEMORY LOSS, DECREASED APPETITE, JOINT PAIN, HALLUCINATIONS, STUPOR, COMA, AND ACNELIKE RASH ON FACE, LEGS, AND TRUN K. ORAL LD-50 (RAT): 0.5-5.0 G/KG. ===================== Ecological Information ===================== Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: >100. DAPHNID EC50 MG/L: 1-10. ALGAL IC50 MG/L: >100. ORGANICS READILY DEGRAD ABLE (>70%): NOT APPLICABLE. POTENTIAL BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 160. BOD5 (APPROXIMATE G/L): 5. POTENTIAL TOXICITY: WASTE TREATMENT MICROORGANISMS EC50 (MG/L): >100. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED. CONTRACT WIT H A LICENSED CHEMICAL DISPOSAL AGENCY. =================== MSDS Transport Information =================== Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE: (716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME), MONDAY THROUGH FRIDAY . ===================== Regulatory Information ===================== SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: NONE Federal Regulatory Information:NOT PROVIDED State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.