MAN-GILL CHEMICAL CO, FORMERLY ECOLAB INC -- LIME-A-WAY -- 6850-00-949-1397
===================== Product Identification ===================== Product ID:LIME-A-WAY MSDS Date:05/01/1988 FSC:6850 NIIN:00-949-1397 === Responsible Party === Company Name:MAN-GILL CHEMICAL CO, FORMERLY ECOLAB INC Address:23000 ST CLAIR AVE City:CLEVELAND State:OH ZIP:44117 Country:US Info Phone Num:216-486-5300 Emergency Phone Num:216-486-5300 Preparer's Name:TECHNICAL MANAGER CAGE:GO241 === Contractor Identification === Company Name:ECOLAB INC, KLENZADE PRODUCTS DIV, ECOLAB CENTER Address:370 WABASHA ST Box:City:ST PAUL State:MN ZIP:55102-1311 Country:US Phone:612-293-2570/800-242-5362 CAGE:91838 Company Name:ECOLAB INC.,MAGNUS CHEMICAL DIV. ECOLAB CENTER Address:370 MABASHA STREET City:ST. PAUL State:MN ZIP:55102-1311 Phone:800-328-0026 CAGE:37733 Company Name:MAN-GILL CHEMICAL CO Address:23000 ST CLAIR AVE City:CLEVELAND State:OH ZIP:44117-5000 Country:US Phone:800-627-6422/216-486-5300 CAGE:GO241 ============= Composition/Information on Ingredients ============= Ingred Name:NITRIC ACID (SARA III) CAS:7697-37-2 RTECS #:QU5775000 Fraction by Wt: <10% Other REC Limits:NONE SPECIFIED OSHA PEL:2 PPM/4 STEL ACGIH TLV:2 PPM/4 STEL; 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PHOSPHORIC ACID (SARA III) CAS:7664-38-2 RTECS #:TB6300000 Fraction by Wt: 10-60% Other REC Limits:NONE SPECIFIED OSHA PEL:1 MG/M3/3 STEL ACGIH TLV:1 MG/M3/3 STEL; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LC50 (RAT) IS 65 PPM (NITRIC ACID) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:SWALLOWED: HARMFUL-CAN DAMAGE TISSUE OF MOUTH, THROAT & STOMACH. EYE: HIGHLY CORROSIVE-CAN CAUSE PERMANENT INJURY. SKIN: HIGHLY CORROSIVE-CAN CAUSE CHEMICAL BURNS. INHALED: VAPOR IS SEVERE IRRITANT TO MUCOUS MEMBRANES & RESPIRATORY TRACT. Effects of Overexposure:IF INHALED, SYMPTOMS MAY BE DELAYED SEVERAL HOURS. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SWALLOWED-DO NOT INDUCE VOMITING. GIVE PLENTY OF WATER OR MILK. EYE-HOLD EYES OPEN & FLOOD WITH WATER FOR 15 MIN. SKIN-REMOVE CONTAMINATED CLOTHING & WASH SKIN THOROUGHLY. INHALED-REMOVE FROM EXPOSURE . IF BREATHING IS LABOURED & CYANOTIC (BLUE) GIVE OXYGEN. IF BREATHING HAS STOPPED PERFORM CPR. SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:NON-COMBUSTIBLE. Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:NON-COMBUSTIBLE. HOWEVER IF PRODUCT IS INVOLVED IN FIRE, HIGHLY TOXIC FUMES WILL BE GIVEN OFF. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN SPILLS USING SAND OR EARTH. NEUTRALIZE WITH LIME OR SODA ASH. WASH TO DRAIN WITH EXCESS WATER. Neutralizing Agent:LIME OR SODA ASH. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL PLACE OUT OF DIRECT SUNLIGHT. STORE AWAY FROM OXIDIZABLE & COMBUSTIBLE MATERIAL & STRONG ALKALI. DANGEROUS GOODS CLASS 8 (CORROSIVE) Other Precautions:POWERFUL OXIDIZING AGENT-CAN REACT WITH ORGANIC MATERIALS. DO NOT MIX WITH CHLORINATED DETERGENTS OR SANITIZERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:CARTRIDGE TYPE RESPIRATOR IF INHALATION RISK EXIST. Ventilation:LOCAL EXHAUST VENTILATION IS PREFERRED. ENSURE ADEQUATE VENTILATION TO MAINTAIN AIR LEVELS BELOW TLV'S. Protective Gloves:PVC OR RUBBER GLOVES. Eye Protection:CHEMICAL SPLASH GOGGLES/FULL FACE SHIELD Other Protective Equipment:PVC APRON, PVC OR RUBBER BOOTS. EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:WASH AFTER USE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:C1 Spec Gravity:1.22 Appearance and Odor:CLEAR, GREEN LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES COMBUSTIBLE MATERIALS AND STRONG ALKALIS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:HIGHLY TOXIC FUMES. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT LOCAL REGULATIONS FOR DISPOSAL. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.