HARRIS WELCO/THERMACOTE WELCO -- E70S-3 -- 3439-01-039-4378
===================== Product Identification ===================== Product ID:E70S-3 MSDS Date:07/01/1993 FSC:3439 NIIN:01-039-4378 === Responsible Party === Company Name:HARRIS WELCO/THERMACOTE WELCO Address:1051 YORK RD City:KING MOUNTAIN State:NC ZIP:28086 Country:US Info Phone Num:704-739-6421 Emergency Phone Num:800-424-9300(CHEMTREC) CAGE:JO222 === Contractor Identification === Company Name:HARRIS WELCO/THERMACOTE WELCO Address:1051 YORK RD Box:828 City:KINGS MOUNTAIN State:NC ZIP:28086 Country:US Phone:704-739-6421 CAGE:JO222 Company Name:J. W. HARRIS CO INC & HARRIS WELCO, DIVISION/J.W. HARRIS CO Address:1051 YORK RD Box:City:KINGS MOUNTAIN State:NC ZIP:28086 Country:US Phone:704-739-6421 CAGE:34920 ============= Composition/Information on Ingredients ============= Ingred Name:CARBON BLACK; (CARBON) CAS:1333-86-4 RTECS #:FF5800000 Fraction by Wt: >0.5% OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 Ingred Name:MANGANESE (SARA 313) CAS:7439-96-5 RTECS #:OO9275000 Fraction by Wt: >2.5% OSHA PEL:5 MG/M3 DUST, C ACGIH TLV:5 MG/M3 DUST Ingred Name:SILICON CAS:7440-21-3 RTECS #:VW0400000 Fraction by Wt: >1.5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:COPPER (SARA 313) (CERCLA) CAS:7440-50-8 RTECS #:GL5325000 Fraction by Wt: >0.5% OSHA PEL:0.1MG/M3 FUME;1 DUST ACGIH TLV:0.2 MG/M3 FUME EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:MOLYBDENUM CAS:7439-98-7 RTECS #:QA4680000 Fraction by Wt: >0.75% OSHA PEL:10 PPM ACGIH TLV:10 PPM Ingred Name:ALUMINUM (SARA 313) CAS:7429-90-5 RTECS #:BD0330000 Fraction by Wt: >0.5% OSHA PEL:15 MG/M3 DUST ACGIH TLV:10 MG/M3 DUST Ingred Name:TITANIUM CAS:7440-32-6 RTECS #:XR1700000 Fraction by Wt: >0.5% ACGIH TLV:10 MG/M3 (MFR) Ingred Name:ZIRCONIUM CAS:7440-67-7 RTECS #:ZH7070000 Fraction by Wt: >0.5% OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3;10 STEL Ingred Name:IRON CAS:7439-89-6 RTECS #:NO4565500 Fraction by Wt: BALANCE ACGIH TLV:5 MG/M3 (MFR) Ingred Name:SUPDAT:IN ELECTRODE, ARE IMPORTANT. CONC OF GIVEN FUME/GAS COMPONENT MAY DECR/INCR BY MANY TIMES ORIGINAL CONC (ING 11) Ingred Name:ING 10:IN ELECTRODE. NEW CMPDS NOT IN ELECTRODE MAY FORM. DECOMP PRODS OF NORMAL OPERATION INCL THOSE (ING 12) Ingred Name:ING 11:ORIGINATING FROM VOLATILIZATION, RXN, OXIDATION OF INGS, PLUS THOSE FROM BASE METAL & COATING. REAS (ING 13) Ingred Name:ING 12:EXPECTED FUME CONSTITUENTS OF PROD COULD INCL PRIMARILY OXIDES OF IRON; SECONDARILY COMPLEX OXIDES OF (ING 14) Ingred Name:ING 13:MANGANESE & SILICON & ALUMINUM. GASEOUS RXN PRODS-CARBON MONOXIDE, CARBON DIOXIDE. OZONE & NITROGEN (ING 15) Ingred Name:ING 14:OXIDES MAY BE FORMED BY RADIA FROM ARC & SHIELDING GASES WHEN EMPLOYED. ONE REC WAY TO DETERM COMPOSITION(ING 16) Ingred Name:ING 15:& QTY OF FUMES & GASES TO WHICH WORKERS ARE EXPOS IS TO TAKE AIR SAMPLE FROM INSIDE WELDERS HELMET/IN (ING 17) Ingred Name:ING 16:WORKING ZONE. SEE AWS F1.1 & AWS F1.2-1985, AVAIL FROM AMERICAN WELDING SOCIETY. SEE AWS PUBLICATION: (ING 18) Ingred Name:ING 17:"FUMES & GASES IN THE WELDING ENVIRONMENT". ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ELECTRIC ARC WELDING MAY CREATE FOLLOWING: FUMES & GASES CAN BE DANGEROUS TO YOUR HEALTH. ARC RAYS CAN INJURE EYES & BURN SKIN. ELECTRIC SHOCK CAN KILL. SIGNS & SYMPTOMS OF EXPOSURE: SHORT TERM-DIZZIN ESS, NAUSEA, DRYNESS & IRRITATION OF NOSE, THROAT, EYES, CHEST TIGHTNESS, FEVER, ALLERGIC REACTION; (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:OVEREXPOSURE TO FUMES-SIDEROSIS POSSIBLE, MAY AFFECT PULMONARY FUNCTION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY AMERICAN RED CROSS. INGEST:CALL MD IMMEDIATELY . EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD . SK IN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . INHAL:REMOVE TO FRESH AIR, OBTAIN MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:WELDING ARCS & SPARKS CAN IGNITE COMBUSTIBLES & FLAMMABLES. REFER TO ANSI Z49.1 FOR FIRE PREVENTION DURING USE OF WELDING & ALLIED PROCEDURES. ================== Accidental Release Measures ================== Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Other Precautions:OTHER PRECS FOR ADDNL SAFETY INFO ON WELDING & CUTTING, SEE ANSI STD Z49.1-1983, SAFETY IN WELDING & CUTTING, WELDING HANDBOOK, VOL 1, SAFE PRACTICES IN WELDING & CUTTING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . MAKE SURE INHALED AIR DOES NOT CONTAIN FUME CONSTITUENTS ABOVE PERMISSIBLE EXPOSURE LEVELS. Ventilation:MAKE SURE INHALED AIR DOES NOT CONTAIN FUME CONSTITUENTS ABOVE PELS. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS . Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health HAZ DECOMP PROD:USED. OTHER FACTORS INCL COATINGS ON METAL BEING WELDED (PAINT, PLATING/ GALVANIZING), NUMBER OF WELDERS & VOL OF WORK AREA AS PRESENCE OF CONTAMS IN ATM. WHEN ELECTRODE IS CONSUMED FU ME & GAS DECOMP PRODS GENERATED ARE DIFF IN PERCENT & FORM FROM INGS LISTED. FUME & GAS DECOMP PRODS & NOT INGS (ING 10) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE. Stability Condition to Avoid:NONE. Hazardous Decomposition Products:COMPOSITION & QUALITY OF WELDING FUMES & GASES ARE DEPENDENT UPON METAL BEING WELDED, PROCESS & ELECTRODE BEING (SUPDAT) ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD PRODUCT RESIDUE, DISPOSABLE CONTAINER OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE W/FEDERAL, STATE & LOCAL RE GULATIONS. ====================================================================== Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.